We have identified 453 compact dense cores in 3 mm continuum emission maps in the ALMA Three-millimetre Observations of Massive Star-forming regions survey, and compiled three catalogues of high-mass star-forming cores. One catalogue, referred to as hyper/ultra compact (H/UC)-H ii catalogue, includes 89 cores that enshroud H/UC H ii regions as characterized by associated compact H40α emission. A second catalogue, referred to as pure s-cHMC, includes 32 candidate hot molecular cores (HMCs) showing rich spectra (N ≥ 20 lines) of complex organic molecules (COMs) and not associated with H/UC-H ii regions. The third catalogue, referred to as pure w-cHMC, includes 58 candidate HMCs with relatively low levels of COM richness and not associated with H/UC-H ii regions. These three catalogues of dense cores provide an important foundation for future studies of the early stages of high-mass star formation across the Milky Way. We also find that nearly half of H/UC-H ii cores are candidate HMCs. From the number counts of COM-containing and H/UC-H ii cores, we suggest that the duration of high-mass protostellar cores showing chemically rich features is at least comparable to the lifetime of H/UC-H ii regions. For cores in the H/UC-H ii catalogue, the width of the H40α line increases as the core size decreases, suggesting that the non-thermal dynamical and/or pressure line-broadening mechanisms dominate on the smaller scales of the H/UC-H ii cores.
We have conducted a line survey toward Orion KL using the Q-band receiver of the Tianma 65 m radio telescope (TMRT), covering 34.8–50 GHz with a velocity resolution between 0.79 and 0.55 km s−1, respectively. The observations reach a sensitivity of the level of 1–8 mK, proving that the TMRT is sensitive for conducting deep-line surveys. In total, 597 Gaussian features are extracted. Among them, 177 radio recombination lines (RRLs) are identified, including 126, 40, and 11 RRLs of hydrogen, helium, and carbon, with a maximum Δn of 16, 7, and 3, respectively. The carbon RRLs are confirmed to originate from photodissociation regions with a V LSR ∼ 9 km s−1. In addition, 371 molecular transitions of 53 molecular species are identified. Twenty-one molecular species of this survey were not firmly detected in the Q band by Rizzo et al., including species such as H2CS, HCOOH, C2H5OH, H 2 13 CO, H2CCO, CH3CHO, CH2OCH2, HCN υ 2 = 1, and CH3OCHO υ t = 1. In particular, the vibrationally excited states of ethyl cyanide (C2H5CN υ13/υ21) are for the first time firmly detected in the Q band. NH3 (15,15) and (16,16) are identified, and they are so far the highest transitions of the NH3 inversion lines detected toward Orion KL. All of the identified lines can be reproduced by a radiative transfer model.
In order to search for shocks in the very early stage of star formation, we performed single-point surveys of SiO J=1-0, 2-1 and 3-2 lines and the H2CO 212 − 111 line toward a sample of 100 high-mass starless clump candidates (SCCs) by using the Korean VLBI Network (KVN) 21-m radio telescopes. The detection rates of the SiO J=1-0, 2-1, 3-2 lines and the H2CO line are $31.0\%$, $31.0\%$, $19.5\%$ and $93.0\%$, respectively. Shocks seem to be common in this stage of massive star formation. The widths of the observed SiO lines (full width at zero power (FWZP)) range from 3.4 to 55.1 km s−1. A significant fraction ($\sim 29\%$) of the detected SiO spectra have broad line widths (FWZP >20 km s−1), which are very likely associated with fast shocks driven by protostellar outflows. This result suggests that about one third of the SiO-detected SCCs are not really starless but protostellar. On the other hand, about 40% of the detected SiO spectra show narrow line widths (FWZP<10 km s−1) probably associated with low-velocity shocks which are not necessarily protostellar in origin. The estimated SiO column densities are mostly 0.31 − 4.32 × 1012 cm−2. Comparing the SiO column densities derived from SiO J=1-0 and 2-1 lines, we suggest that the SiO molecules in the SCCs may be in the non-LTE condition. The SiO abundances to H2 are usually 0.20 − 10.92 × 10−10.
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