Superhydrophobic
polyurethane foam (PUF) is prepared by surface coating of halloysite
nanotubes. The nanotubes were first modified by surface grafting with
hexadecyltrimethoxysilane, followed by assembly on the PUF by
dip coating. This treatment makes the water contact angle of the modified
PUF higher than 150°. The modified foam has a highly selective
absorption of oils and organic solvents. The absorption ratios of
the modified PUF for chloroform and dichloroethane reached 104 and
74, respectively. Such superhydrophobic foam can maintain the oil
absorption performance even after 10 absorption–squeezing cycles,
demonstrating good recyclability. The modified foam can pick up oil
or organic solvent continuously and quickly from water’s surface.
This hydrophobic nanotube coating also enhances the flame retardancy
of the PUF, and the modified foam will extinguish itself maintaining
its integrity. The preparation method for hydrophobic and flame-retardant
PUF by coating with natural clay nanotubes is a simple process and
promises scalable applications in oil–water separation.
DNA tetrahedron nanostructures (DTNSs) were prepared to improve the accuracy of cancer diagnosis through real-time monitoring and imaging three intracellular miRNAs, as well as to realize cancer therapy induced by miRNA silencing.
Gold nanorods (GNRs) and doxorubicin (DOX) were loaded into the lumen of halloysite nanotubes (HNTs) via a rapid synthesis process (2 min) and physical adsorption. The targeting molecules of folic acid (FA) are then conjugated to HNTs via reactions with bovine serum albumin (BSA).
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