No abstract

A theoretical study of the complexes formed by hypohalous acids (HOX, X = F, Cl, Br, I, and At) with three nitrogenated bases (NH 3, N 2, and NCH) has been carried out by means of ab initio methods, up to MP2/aug-cc-pVTZ computational method. In general, two minima complexes are found, one with an OH...N hydrogen bond and the other one with a X...N halogen bond. While the first one is more stable for the smallest halogen derivatives, the two complexes present similar stabilities for the iodine case and the halogen-bonded structure is the most stable one for the hypoastatous acid complexes.

It is well known that certain variables can bias judgements about the perceived contingency between an action and an outcome, making them depart from the normative predictions. For instance, previous studies have proven that the activity level or probability of responding, P(R), is a crucial variable that can affect these judgements in objectively noncontingent situations. A possible account for the P(R) effect is based on the differential exposure to actual contingencies during the training phase, which is in turn presumably produced by individual differences in participants' P(R). The current two experiments replicate the P(R) effect in a free-response paradigm, and show that participants' judgements are better predicted by P(R) than by the actual contingency to which they expose themselves. Besides, both experiments converge with previous empirical data, showing a persistent bias that does not vanish as training proceeds. These findings contrast with the preasymptotic and transitory effect predicted by several theoretical models.