Active anhydrite hydration during weathering leading to crystallisation of secondary gypsum and significant volume expansion was investigated and documented by the authors at three sites: the environs of Walkenried (Germany), Dingwall (Canada), and Pisky (Ukraine). As a result of these processes, peculiar landscape forms were created: hydration domes and ridges with empty internal chambers, some of them large enough to be called hydration caves (German: Quellungshöhlen). Currently, there are only four recognised sites on Earth featuring such a unique landscape and with a large group of hydration caves in one place (the fourth site is in the Alebastrovyye Islands, Russia). These sites constitute a particularly valuable geological and geomorphological heritage, including potential geosites and geomorphosites which require special protection. Actively growing hydration domes and caves change shape and size within a short time span, on the scale of months, years, or decades. Their study and proper protection require these changes to be monitored. Several different methods of documentation were applied in the field in order to document continuing morphological changes. The practical aspects of the use of each of these methods were assessed, demonstrating that the photogrammetric methods offer the greatest utility; not only are they the most efficient (fast and sufficiently precise) but also, compared with other methods, they yielded the most complete results. The key documentation of outcrops in Canada and Ukraine was executed with the application of terrestrial photogrammetry at Pisky (GoPro camera) and aerial photogrammetry at Dingwall (unmanned aerial vehicle). Application of these methods enabled the recording of the morphology associated with the hydration process in the form of 2.5D and 3D models as well as of orthophotomaps. The maps and the models were created using the Photoscan programme. The authors demonstrate that the photogrammetric models can be used for spatial morphological analysis of hydration forms in the ArcGIS programme. Repetition of this documentation in future will enable analysis of the morphological changes expected to occur during the progressive expansive hydration of anhydrite.
In the Dingwall gypsum quarry in Nova Scotia, Canada, operating in 1933–1955, the bedrock anhydrite deposits of the Carboniferous Windsor Group have been uncovered from beneath the secondary gypsum beds of the extracted raw material. The anhydrite has been subjected to weathering undergoing hydration (gypsification), transforming into secondary gypsum due to contact with water of meteoric derivation. The ongoing gypsification is associated with a volume increase and deformation of the quarry bottom. The surface layer of the rocks is locally split from the substrate and raised, forming spectacular hydration relief. It shows numerous domes, ridges and tepee structures with empty internal chambers, some of which represent unique hydration caves (swelling caves, Quellungshöhlen). The petrographic structure of the weathering zone has been revealed by macro- and microscopic observations. It was recognized that gypsification commonly starts from a developing network of tiny fractures penetrating massive anhydrite. The gypsification advances from the fractures towards the interior of the anhydrite rocks, which are subdivided into blocks or nodules similar to corestones. Characteristic zones can be recognized at the contact of the anhydrite and the secondary gypsum: (1) massive and/or microporous anhydrite, (2) anhydrite penetrated by tiny gypsum veinlets separating the disturbed crystals and their fragments (commonly along cleavage planes), (3) gypsum with scattered anhydrite relics, and (4) secondary gypsum. The secondary gypsum crystals grow both by replacement and displacement, and also as cement. Displacive growth, evidenced by abundant deformation of the fragmented anhydrite crystals, is the direct cause of the volume increase. Crystallization pressure exerted by gypsum growth is thought to be the main factor generating volume increase and, consequently, also the formation of new fractures allowing water access to “fresh” massive anhydrite and thus accelerating its further hydration. The expansive hydration is taking place within temperature range from 0 to ~30 °C in which the solubility of gypsum is lower than that of anhydrite. In such conditions, dissolving anhydrite yields a solution supersaturated with gypsum and the dissolution of anhydrite is simultaneous with in situ replacive gypsum crystallization. Accompanying displacive growth leads to volume increase in the poorly confined environment of the weathering zone that is susceptible to upward expansion.
The gypsum-anhydrite rocks in the abandoned quarry at Dingwall (Nova Scotia, Canada) are subjected to physical and chemical weathering, including hydration of the anhydrite, i.e., its transformation into secondary gypsum under the influence of water. This process is known to lead to the localized volume increase of the rock and the formation of spectacular hydration landforms: domes, tepees and ridges. Cavities appearing in the interior of these domes are often unique hydration caves (Quellungshöhlen in German). For the first time, this paper gives detailed geomorphometric characteristics of the 77 dome- and tepee-like hydration landforms growing today at Dingwall based on their digital surface models and orthophotomaps, made with the method of photogrammetry integrated with direct measurements. The length of hydration landforms varies from 1.86 to 23.05 m and the relative height varies from 0.33 to 2.09 m. Their approximate shape in a plan view varies from nearly circular, through oval, to elongated with a length-to-width ratio rarely exceeding 5:2. Length, width and relative height are characterized by moderate mutual correlation with proportional relations expressed by linear equations, testifying that the hydration landforms generally preserve the same or very similar shape independent of their sizes. The averaged thickness of the detached rock layer ranges from 6 to 46 cm. The size of the forms seems to depend on this thickness—the forms larger in extent (longer) generally have a thicker detached rock layer. Master (and other) joints and, to a lesser extent, layering in the bedrock influence the development of hydration landforms, particularly by controlling the place where the entrances are open to internal cavities or caves. Three structural types of the bedrock influencing the growth of hydration forms were recognized: with master joints, with layering and with both of them. The latter type of bedrock has the most complex impact on the morphology of hydration landforms because it depends on the number of master joint sets and the mutual orientation of joints and layering, which are changeable across the quarry. The durability of the hydration forms over time depends, among others, on the density of fractures in the detached rock layer.
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