Inelastic transport through a single magnetic molecule weakly coupled to metallic leads is studied theoretically. We consider dynamical processes that are relevant for writing, storing, and reading spin information in molecular memory devices. Magnetic anisotropy is found to be crucial for slow spin relaxation. In the presence of anisotropy we find giant spin amplification: The spin accumulated in the leads if a bias voltage is applied to a molecule prepared in a spin-polarized state can be made exponentially large in a characteristic energy divided by temperature. For one ferromagnetic and one paramagnetic lead the molecular spin can be reversed by applying a bias voltage even in the absence of a magnetic field. We propose schemes for reading and writing spin information based on our findings.
We present a theoretical analysis of a novel cavity electromechanical system where a mechanical resonator directly modulates the damping rate kappa of a driven electromagnetic cavity. We show that via a destructive interference of quantum noise, the driven cavity can effectively act like a zero-temperature bath irrespective of the ratio kappa/omega_{M}, where omega_{M} is the mechanical frequency. This scheme thus allows one to cool the mechanical resonator to its ground state without requiring the cavity to be in the so-called good cavity limit kappa << omega_{M}. The system described here could be implemented directly using setups similar to those used in recent experiments in cavity electromechanics.
We consider transport through a single N@C60 molecule, weakly coupled to metallic leads. Employing a density-matrix formalism we derive rate equations for the occupation probabilities of many-particle states of the molecule. We calculate the current-voltage characteristics and the differential conductance for N@C60 in a break junction. Our results reveal Coulomb-blockade behavior as well as a fine structure of the Coulombblockade peaks due to the exchange coupling of the C60 spin to the spin of the encapsulated nitrogen atom.
Transport and non-equilibrium magnetization in monolayers of magnetic molecules subject to a bias voltage are considered. We apply a master-equation approach going beyond the sequentialtunneling approximation to study the Coulomb-blockade regime. While the current is very small in this case, the magnetization shows changes of the order of the saturation magnetization for small variations of the bias voltage. Inelastic cotunneling processes manifest themselves as differentialconductance steps, which are accompanied by much larger changes in the magnetization. In addition, the magnetization in the Coulomb-blockade regime exhibits strong signatures of sequential tunneling processes de-exciting molecular states populated by inelastic cotunneling. We also consider the case of a single molecule, finding that cotunneling processes lead to the occurrence of magnetic sidebands below the Coulomb-blockade threshold. In the context of molecular electronics, we study how additional spin relaxation suppresses the fine structure in transport and magnetization.
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