The synthesis of ruthenium nanoparticles (RuNPs) using secondary phosphine oxides (SPOs) as ligands is reported. These easily accessible ligands allow the formation of small nanoparticles in the size range of 1-2 nm which display a high efficiency for hydrogenation of aromatics with TOFs up to 2700 mol h À1 .Scheme 1 SPOs tautomeric equilibrium, chelate formation, and heterolytic cleavage of H 2 .Scheme 2 Secondary phosphine oxides used.

Recently, it became clear that relaxation effects in amorphous ices play a very important role that has previously been overlooked. The thermodynamic history of amorphous samples strongly affects their transition behavior. In particular, well-relaxed samples show higher thermal stability, thereby providing a larger window to investigate their glass transitions. We here present neutron scattering experiments using fixed elastic window scans on relaxed forms of amorphous ice, namely expanded high density amorphous ice (eHDA), a variant of low density amorphous ice (LDA-II) and hyperquenched glassy water (HGW). These amorphous ices are expected to be true glassy counterparts of deeply supercooled liquid water, therefore fast precursor dynamics of structural relaxation are expected to appear below the calorimetric glass transition temperature. The Debye-Waller factor shows a very weak sub-T(g) anomaly in some of the samples, which might be the signature of such fast precursor dynamics. However, we cannot find this behavior consistently in all samples at all reciprocal length scales of momentum transfer.

(2)H NMR spectra, spin-lattice relaxation, and stimulated echoes have been measured in polycrystalline ice II in the temperature range of 84-145 K at ambient pressure. From the spectra we obtain the quadrupole coupling constant in ice II, e(2)qQ/h = (225.7+/-1.2) kHz, and the asymmetry parameter, eta = 0.118+/-0.006. At 145 K, a phase transition of ice II into ice I(c) is observed by a change of both, its spectral and relaxation behavior. The spin-lattice relaxation in ice II is bimodal, showing two components of approximately the same weight. The fast relaxing part of the recovery curve progresses monoexponentially and the temperature dependence of its mean relaxation time corresponds to an unusually low activation energy of 2.3 kJ mol(-1). The slowly relaxing part, displaying average relaxation times of about 4000 s, is significantly stretched with a Kohlrausch parameter of 0.6 and shows no temperature dependence. The stimulated echo experiments show a temperature independent correlation decay. The analysis of intermediate states indicates that no small-angle motions are involved in the underlying process. Both findings exclude an interpretation in terms of molecular motion. Instead, spin diffusion in the deuteron system has to be considered as the origin of the phenomena observed in the stimulated echo experiments.

The high-frequency reorientation dynamics of O-(2)H bonds is investigated in various amorphous ices including eHDA (expanded high density amorphous ice), LDA-II (low density amorphous ice II) and HGW (hyperquenched glassy water) using (2)H-NMR spin-lattice relaxation as a local probe. Both low density forms, HGW and LDA-II, show similar spin-lattice relaxation but differ in the thermal stability with respect to the transition into crystalline cubic ice I(c). HGW already transforms slightly above 135 K whereas LDA-II crystallizes at 150 K. eHDA is distinguishable from other high density amorphous ices in its thermal stability and spin-lattice relaxation. Its relaxation times are much larger compared to those of VHDA (very high density amorphous ice) and uHDA (unrelaxed high density amorphous ice). eHDA does not show annealing effects, transforms sharply into LDA-II above 123 K and provides higher thermal stability as compared to other high density forms.

The postulated glass-liquid transition of low density amorphous ice (LDA) is investigated with deuteron NMR stimulated echo experiments. Such experiments give access to ultra-slow reorientations of water molecules on time scales expected for structural relaxation of glass formers close to the glass-liquid transition temperature. An involved data analysis is necessary to account for signal contributions originating from a gradual crystallization to cubic ice. Even if some ambiguities remain, our findings support the view that pressure amorphized LDA ices are of glassy nature and undergo a glass-liquid transition before crystallization.