No abstract

The project FUXYA2020 was intended to design and prototype a low-cost basic energy dispersive X-ray fluorescence spectrometer for all those cases where there is not enough financial support to buy a commercial device. Indeed, home-made instruments are ideal when funds are low but constant over the years, as this approach allows the costs to be spread over a longer period of time. The FUXYA2020 was intended mostly for cultural heritage (CH) applications: we optimized the geometry to meet the requirements for both low Z matrix objects, such as glasses and ceramics, and medium-high Z materials, such as metals; besides, we designed a positioning system through Arduino components to obtain good results and repeatability for samples with a complex geometry. The FUXYA2020’s performance was tested both for qualitative and quantitative analyses, the former on pigment layers, and the latter on gold-based certified alloys, exploiting Axil-QXAS software for data elaboration. The classification of ancient ceramics based on multivariate analysis obtained through R environment was also carried out. The qualitative data on pigments have also been compared with the same data obtained by a commercial XRF spectrometer, demonstrating how our very simple and inexpensive prototype can be of great help for a rapid and reliable characterization of cultural heritage materials whenever commercial devices are unaffordable.

Pulsed thermography was exploited to identify the presence of glass defects in order to get an indication of the conservation status of archaeological glass. Indeed, the process of degradation in artifacts subjected to centuries of burial can be of great relevance. More specifically, we evaluated the potential of pulsed thermography to map the presence of flakes in archaeological glass. This was achieved by comparing different heating setups and signal-processing algorithms. Tests were carried out previously on glass mockups with surface defects and then on archaeological artifacts.

The process of degradation in artefacts subjected to centuries of burial can be of great relevance above all in archaeological glass. Infrared thermography is a non-destructive method allowing to map the defects of the glass substrate, both produced during its manufacturing (e.g., bubbles and inclusions) and due to ageing. This research is focused on the use of different flash thermography methods for the mapping of superficial flakes on Roman glasses dating back to the I and II century A.D. The effectiveness of active thermography methods is evaluated to map degraded portions of archaeological glass considering their semitransparency and specific optical absorption.