Studies in actual urban settings that integrate chemical reaction modeling, radiation, and particular emissions are mandatory to evaluate the effects of traffic-related air pollution on street canyons. In this paper, airflow patterns and reactive pollutant behavior for over 24 h, in a realistic urban canyon in Osaka City, Japan, was conducted using a computational fluid dynamics (CFD) model coupled with a chemical reaction model (CBM-IV). The boundary conditions for the CFD model were obtained from mesoscale meteorological and air quality models. Inherent street canyon processes, such as ground and wall radiation, were evaluated using a surface energy budget model of the ground and a building envelope model, respectively. The CFD-coupled chemical reaction model surpassed the mesoscale models in describing the NO, NO2, and O3 transport process, representing pollutants concentrations more accurately within the street canyon since the latter cannot capture the local phenomena because of coarse grid resolution. This work showed that the concentration of pollutants in the urban canyon is heavily reliant on roadside emissions and airflow patterns, which, in turn, is strongly affected by the heterogeneity of the urban layout. The CFD-coupled chemical reaction model characterized better the complex three-dimensional site and hour-dependent dispersion of contaminants within an urban canyon.

Traffic-related air pollution in street canyons can cause health problems for pedestrians. In order to clarify the behavior of reactive pollutants, such as NOx and O3, in street canyons, a computational fluid dynamics (CFD) model coupled with a chemistry model and tree canopy model was developed, and then, a set of numerical experiments were performed to investigate the impacts of chemical reactions and aerodynamic effects of trees planted in a canyon. The results were compared with the observation data. Through the results of the numerical experiments designed to simulate a realistic urban street canyon, it was found that chemical reactions have a dominant impact on the NO/NO2 ratio and O3 concentration. While the tree canopy had little impact on the NO/NO2 ratio, it had a moderate impact on the flow field in the canyon and the amount of NOx and O3 in the canyon. In accordance with the aerodynamic effects of tree canopies, the local NOx concentration in the experiments increased and decreased by up to 51% and 11%, respectively. The current findings of this study demonstrate the utility of the proposed model for conducting air quality investigations in urban areas.