Selective-area epitaxy is used to form three-dimensional (3D) GaN structures providing semipolar crystal facets. On full 2-in. sapphire wafers we demonstrate the realization of excellent semipolar material quality by introducing inverse GaN pyramids. When depositing InGaN quantum wells on such a surface, the specific geometry influences thickness and composition of the films and can be nicely modeled by gas phase diffusion processes. Various investigation methods are used to confirm the drastically reduced piezoelectric polarization on the semipolar planes. Complete electrically driven light-emitting diode test structures emitting in the blue and blue/green spectral regions show reasonable output powers in the milliwatt regime. Finally, first results of the integration of the 3D structures into a conventional laser design are presented
Semipolar ð1122Þ oriented GaN has been grown on a prestructured r-plane sapphire substrate. By using silicon doped marker layers (MLs) we have been able to monitor the growth evolution of the stripes until coalescence. With that technique we correlated the growth type (direction) with the results of cathodoluminescence (CL) and transmission electron microscopy. Both characterization methods show only a few defects for the major part of the structure and a relatively high defect density for material grown in a-direction at one side of the stripes. It is shown that during coalescence these defects are mainly terminated resulting in a flat, planar ð1122Þ GaN layer with strongly reduced defect density. Additionally, X-ray diffraction (XRD) measurements show the high quality of these layers.
The authors demonstrate the fabrication and evaluation of bright semipolar GaInN∕GaN blue light emitting diodes (LEDs). The structures are realized by growing five GaInN∕GaN quantum wells on the {11¯01} side facets of selectively grown n-GaN stripes with triangular shape running along the ⟨112¯0⟩ direction covered with a Mg-doped GaN top layer. The growth was done by metal organic vapor phase epitaxy using a conventional [0001] sapphire substrate. The devices have circular mesa structures with diameters between 70 and 140μm. Continuous wave on-wafer optical output powers as high as 700μW and 3mW could be achieved under dc conditions for 20 and 110mA, respectively. The current dependent blueshift of the peak emission wavelength caused by screening effects of the piezoelectric field was only 1.5nm for currents between 1 and 50mA. This is less than half the value measured on c-plane LEDs and confirms the reduced piezoelectric field in our LED structures.
We report on the growth of planar semipolar ͑1011͒ GaN on ͑1123͒ prepatterned sapphire. This is a method that allows the growth of semipolar oriented ͑1011͒ GaN on large scale. Using x-ray diffraction only the peaks of the desired ͑1011͒ plane could be observed. Scanning electron, transmission electron, and atomic force microscopy measurements show an atomically flat surface. Further investigations using photoluminescence spectroscopy show spectra that are dominated by the near band edge emission. The high crystal quality is furthermore confirmed by the small full width at half maximum values of x-ray rocking curve measurements of less than 400 arcsec.
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