There is considerable interest in using crude glycerin from biodiesel production as a heating fuel. In this work crude glycerin was emulsified into fuel oil to address difficulties with ignition and sustained combustion. Emulsions were prepared with several grades of glycerin and two grades of fuel oil using direct and phase inversion emulsification. Our findings reveal unique surfactant requirements for emulsifying glycerin into oil; these depend on the levels of several contaminants, including water, ash, and components in MONG (matter organic non-glycerin). A higher hydrophile-lipophile balance was required for a stable emulsion of crude glycerin in fuel oil compared to water in fuel oil. The high concentration of salts from biodiesel catalysts generally hindered emulsion stability. Geometric close-packing of micelles was carefully balanced to mechanically stabilize emulsions while also enabling low viscosity for pumping and fuel injection. Phase inversion emulsification produced more stable emulsions than direct emulsification. Emulsions were tested successfully as fuel for a waste oil burner.

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We have investigated the vibrational population relaxation dynamics and state-dependent orientational relaxation behavior of perylene in micelles and vesicles formed using the same amphiphile(s). Decanoic acid and its conjugate base sodium decanoate can form either micelle or vesicle structures in aqueous solution depending on amphiphile concentration and solution pH. The issue of interest in this work is whether or not different assemblies of a given amphiphile manifest different efficiencies with the dissipation of energy. Vibrational population relaxation data show that initial energy flow from the chromophore to the amphiphile aliphatic chains is more efficient in micelles than in vesicles. Longer time scale relaxation, gauged by transient local heating induced by the dissipation of excess energy from perylene shows that the local environment formed by micelles experiences greater temperature change than the local environment formed by vesicles. This finding suggests that the strength of coupling between the bath and the amphiphiles differs for the two structural motifs.