Quartz-crystal resonators were coated with a layer of alumina nanopores in order to allow for simultaneous measurement of density and viscosity of a liquid. Whereas the motion of the liquid contained in the pores is locked to the movement of the crystal, the liquid located above the surface experiences internal shear. The latter portion of the liquid dissipates energy, thereby increasing the bandwidth of the resonance. Based on the increase in bandwidth, viscous loading and mass loading can be distinguished, allowing for an independent determination of the density and the viscosity of Newtonian liquids.
The copolymerization behavior of mixtures of an acidic and a basic monomer were studied as a function of the monomer feed composition. The four systems investigated in this way comprised APSA/1‐VIm, APSA/4‐VP, APSA/DAMA, and SSA/1‐VIm. The corresponding polyelectrolytes were obtained by free radical polymerization of the monomer mixtures in solution, while the isolated monomeric salts of equivalent amounts of both monomers were prone to spontaneous polymerization. For APSA/1‐VIm, APSA/4‐VP, and APSA/DAMA, a donor‐acceptor relationship was found, whereas for SSA/1‐VIm the SSA was favorably incorporated over all feed ratios. High Tg and complex viscosity data indicated a considerable degree of ionic, thermally reversible crosslinking within the polymers that were thermally stable up to at least 230 °C.magnified image
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