Upgrading and utilizing low-grade iron ore is of great practical importance to improve the strategic security of the iron ore resource supply. In this study, a thermal analysis–infrared (IR) analysis–in-situ IR method was used to investigate the reaction mechanism and kinetics of Daxigou siderite. Experiments were conducted using a conveyor bed magnetization roasting process (CBMRP) to investigate the magnetization of siderite. Multi-stage magnetic separation processes were adopted to extract magnetite. The results show that simultaneously the iron carbonate in siderite decomposes, and magnetite is formed between 364 °C and 590 °C under both inert and reducing atmospheres. The activation energy of the magnetization roasting reaction is 106.1 kJ/mol, consistent with a random nucleation and growth reaction mechanism. Magnetization roasting at 750–780 °C for approximately 3.5 s in the CBMRP results in a magnetic conversion rate of >0.99% of the iron minerals in the siderite. A beneficiation process of one roughing, one sweeping, and three cleaning processes was adopted. A dissociation particle size of −400 mesh accounting for 94.78%, a concentrate iron grade of 62.8 wt.%, and a recovery of 68.83% can be obtained. Overall, a theoretical and experimental basis is presented for the comprehensive utilization of low-grade siderite.

The hydration of M-S-H prepared using silica fume (SF) and dead-burned MgO cured at 20 °C, 50 °C, and 80 °C was investigated, and the properties and performance of this M-S-H were measured. The formation of M-S-H was characterized using XRD, FTIR, TGA, and 29Si MAS-NMR. Results show that the compressive strength of paste prepared using MgO calcined at 1450 °C for 2 h reached 25 MPa after 28 d. The shrinkage of mortar made with low reactivity MgO was lower than that made with high reactivity MgO. The pH value of MgO/SF paste mixed with dead-burned MgO did not exceed 10.4 at room temperature. The shrinkage of M-S-H prepared using dead-burned MgO was less than that prepared using more active MgO, and its strength did not decrease over time. No (or only a small amount of) Mg(OH)2 was formed, which is why the strength of M-S-H prepared with dead-burned MgO continually increased, without decreasing. The promotion of curing temperature favor process of MgO hydration and is beneficial for degree of silica polymerization. The sample cured in 50 °C water showed the highest relative degree of reaction.

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