Structural, electronic, and chemical nanoscale modifications of transition metal dichalcogenide monolayers alter their optical properties. A key missing element for complete control is a direct spatial correlation of optical response to nanoscale modifications due to the large gap in spatial resolution between optical spectroscopy and nanometer-resolved techniques. Here, we bridge this gap by obtaining nanometer-resolved optical properties using electron spectroscopy at cryogenic temperatures, specifically electron energy loss spectroscopy for absorption and cathodoluminescence for emission, which are then directly correlated to chemical and structural information. In an h-BN/WS2/h-BN heterostructure, we observe local modulation of the trion (X–) emission due to tens of nanometer wide dielectric patches. Trion emission also increases in regions where charge accumulation occurs, close to the carbon film supporting the heterostructures. The localized exciton emission (L) detected here is not correlated to strain above 1%, suggesting point defects might be involved in their formation.

We report on the fabrication of high-power, high-spectral-purity GaSb-based laterally coupled distributed feedback (LC-DFB) lasers emitting at 2 μm. Second-order Chromium-Bragg-gratings are fabricated alongside the ridge waveguide by lift off. Due to the introduction of gain coupling, the lasers exhibit a stable single mode operation [side-mode suppression ratio (SMSR) >40 dB] from 10 °C to 50 °C and the maximum SMSR is as high as 53 dB. At a heat-sink temperature of 10 °C, the lasers emit more than 40 mW continuous-wave in a single longitudinal mode. A high external quantum efficiency of 48% is obtained, resulting in a notable increase in power conversion efficiency peaking at 13%. The lasers achieve a comparable output power with that of the index-coupled LC-DFB lasers, while maintaining a better single mode performance. Thus, we prove the feasibility of the metal-grating LC-DFB structure to achieve high-power, frequency-stable semiconductor lasers through a simpler and much more convenient way.