In recent years, cabled ocean observation technology has been increasingly used for deep sea in situ research. As sophisticated sensor or measurement system starts to be applied on a remotely operated vehicle (ROV), it presents the requirement to maintain a stable condition of measurement system cabin. In this paper, we introduce one kind of ROV-based Raman spectroscopy measurement system (DOCARS) and discuss the development characteristics of its cabin condition during profile measurement process. An available and straightforward modeling methodology is proposed to realize predictive control for this trend. This methodology is based on the Autoregressive Exogenous (ARX) model and is optimized through a series of sea-going test data. The fitting result demonstrates that during profile measurement processes this model can availably predict the development trends of DORCAS’s cabin condition during the profile measurement process.
This study explored the influence of choosing a nonhydrostatic dynamical core or a hydrostatic dynamical core in the weather research and forecasting (WRF) model on the intensity and structure of simulated tropical cyclones (TCs). A comparison of cloud-resolving simulations using each core revealed significant differences in the TC simulations. In comparison with the nonhydrostatic simulation, the hydrostatic simulation produced a stronger and larger TC, associated with stronger convective activity. A budget analysis of the vertical momentum equation was conducted to investigate the underlying mechanisms. Although the hydrostatic dynamical core was used, the vertical motion was not in strict hydrostatic balance because of the existence of the vertical perturbation pressure gradient force, local buoyancy force, water loading, and sum of the Coriolis and diffusion effects. The contribution of the enhanced vertical perturbation pressure gradient force was found to be more important for stronger upward acceleration in the eyewall in the hydrostatic simulation than in the nonhydrostatic simulation. This is because it leads to intensified convection in the eyewall that releases more latent heat, which induces a larger low-level radial pressure gradient and inflow motion, and eventually leads to a stronger storm.
In this paper, by means of Cu(2+) converting to Cu, the sub-ppb detection of copper in aqueous solution was successfully achieved using laser-induced breakdown spectroscopy (LIBS), and the sensitivity was found depending on the voltage applied for the deposition. With increasing voltage, the minimum detectable concentration was significantly lowered, while the signal intensity instability was increased. In order to reduce the impact from the intensity fluctuation, an estimation method was developed to determine the copper concentration via comparing minimum detectable concentrations. The obtained results suggest this method is a potential way toward quantitative analysis.
Depth profiling investigation plays an important role in studying the dynamic processes of the ocean. In this paper, a newly developed hyphenated underwater system based on multi-optical spectrometry is introduced and used to measure seawater spectra at different depths with the aid of a remotely operated vehicle (ROV). The hyphenated system consists of two independent compact deep-sea spectral instruments, a deep ocean compact autonomous Raman spectrometer and a compact underwater laser-induced breakdown spectroscopy system for sea applications (LIBSea). The former was used to take both Raman scattering and fluorescence of seawater, and the LIBS signal could be recorded with the LIBSea. The first sea trial of the developed system was taken place in the Bismarck Sea, Papua New Guinea, in June 2015. Over 4000 multi-optical spectra had been captured up to the diving depth about 1800 m at maximum. The depth profiles of some ocean parameters were extracted from the captured joint Raman–fluorescence and LIBS spectra with a depth resolution of 1 m. The concentrations of [Formula: see text] and the water temperatures were measured using Raman spectra. The fluorescence intensities from both colored dissolved organic matter (CDOM) and chlorophyll were found to be varied in the euphotic zone. With LIBS spectra, the depth profiles of metallic elements were also obtained. The normalized intensity of atomic line Ca(I) extracted from LIBS spectra raised around the depth of 1600 m, similar to the depth profile of CDOM. This phenomenon might be caused by the nonbuoyant hydrothermal plumes. It is worth mentioning that this is the first time Raman and LIBS spectroscopy have been applied simultaneously to the deep-sea in situ investigations.
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