Nitrogen
oxides (NO
x
) have attracted
extensive concerns as a secondary aerosol precursor in recent years.
Solar-induced photocatalytic oxidation is a promising strategy for
of NO
x
removal nowadays. In this contribution,
nitrogen-doped carbon quantum dots (N-CQDs)/CaTiO3 composite
was synthesized using a facile hydrothermal process. The incorporation
of N-CQDs to CaTiO3 facilitates the transfer of electrons
and divorce of photogenerated carriers. NO temperature-programmed
desorption (NO-TPD) demonstrated that the presence of N-CQDs was conducive
to the NO adsorption in comparison with the pristine CaTiO3. The composite catalyst demonstrated much better photocatalytic
performance than CaTiO3 and P25 did in regard to gaseous
NO removal and NO2 selectivity under visible light irradiation.
Both •O2
– and •OH are believed
to make a major contribution to NO removal. The role of N-CQDs was
unraveled in the photocatalytic reaction of NO elimination over N-CQDs/CaTiO3 samples. This study provides insight into the composite catalyst
N-CQDs/CaTiO3 in photocatalytic reactions and applications.
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