[1] A field experiment was carried out in summer 2002 on an oceanographic platform near the coast of Crimea, in the Black Sea. For the first time, the spectral volume scattering function (VSF) was measured for a wide range of scattering angles (i.e., from 0.6 to 177.3 degrees) using a recently developed device. Our analysis revealed that the mineral particles are the primary component influencing the scattering and backscattering coefficient in the study area. The good correlation obtained between the backscattering coefficient b bp and the nonalgal particles absorption coefficient showed that the absorption efficiency of the mineral particles is high in the second half of the experiment. The ratio Chla/c p (where Chla is the chlorophyll a concentration and c p is the beam attenuation coefficient) did not correlate with the backscattering ratio and thus could not be used in this experiment as an alternative proxy to estimate the bulk composition of the particles. The spectral variation of b p (the scattering coefficient) and b bp (the backscattering coefficient) was less steep than what can be found in the open ocean waters. That was explained by the influence of the absorption on the scattering process, especially in the blue, as a consequence of the anomalous dispersion. The average backscattering ratiõ b bp varied spectrally within 4%. Nevertheless, a high spectral variability ofb bp (around 30%) was observed suggesting that the use of a flat spectral variation is not accurate in coastal zones.

[1] The particulate backscattering coefficient b bp is an inherent optical property that plays a central role in studies of ocean color remote sensing. Because of practical difficulties associated with measurements of the volume scattering function (VSF) over the whole backward hemisphere, b bp is currently derived using fixed-angle backscattering sensors and applying a conversion factor for particulate backscattering, referred to as c p . The underlying assumptions of the fixed-angle approach are as follows: (1) in the green band, c p is fairly constant in the angular range 100°-150°and (2) for a fixed scattering angle, c p is wavelength-independent. In this study we investigated the variability of c p based on spectral measurements of the full VSF, both in situ and for algal culture in the laboratory. The in situ data used in our study were acquired in a coastal environment outside of phytoplankton blooms, whereas the laboratory data were representative for phytoplankton bloom conditions in oceanic waters. At 555 nm, c p was found to vary significantly in the angular range 100°-130°, and at 140°, c p was found to be weakly variable in nonblooming waters only. The spectral variability of c p was studied for the first time, and the spectral slopes of c p , measured in situ, were found to vary within ±6%. Under the assumption that c p (140°) is wavelength-independent, the induced error in the estimates of b bp was found to be lower than 10%. The algal culture showed a much higher spectral variability in c p (±20%), which induced an error in the estimates of b bp up to ±25.8%.Citation: Chami, M., E. Marken, J. J. Stamnes, G. Khomenko, and G. Korotaev (2006), Variability of the relationship between the particulate backscattering coefficient and the volume scattering function measured at fixed angles,

The spectral volume scattering function (VSF) was measured in a coastal environment from 0.6 degrees to 177.3 degrees by use of a recently developed device. The spectral variations of the particulate VSF and phase function (i.e., ratio of the VSF to the scattering coefficient) were examined as a function of the scattering angle. The angular dependency of both VSF and phase- function spectra was highly sensitive to the absorption and to the size distribution of the particles. As a result, the use of spectrally neutral phase functions in radiative-transfer modeling is questioned.

In-situ sodar and lidar measurements were coupled with numerical simulations for studying a sea-breeze event in a flat coastal area of the North Sea. The study's aims included the recognition of the dynamics of a sea-breeze structure, and its effects on the lower troposphere stratification and the three-dimensional (3D) pollutant distribution. A sea breeze was observed with ground-based remote sensing instruments and analysed by means of numerical simulations using the 3D non-hydrostatic atmospheric model Meso-NH. The vertical structure of the lower troposphere was experimentally determined from the lidar and sodar measurements, while numerical simulations focused on the propagation of the sea breeze inland. The sea-breeze front, the headwind, the thermal internal boundary layer, the gravity current and the sea-breeze circulation were observed and analysed. The development of a late stratification was also observed by the lidar and simulated by the model, suggesting the formation of a stable multilayered structure. The transport of passive tracers inside the sea breeze and their redistribution above the gravity current was simulated too. Numerical modelling showed that local pollutants may travel backward to the sea above the gravity current at relatively low speed due to the shearing between the landward gravity current and the seaward synoptic wind. Such dynamic conditions may enhance an accumulation of pollutants above coastal industrial areas.

Scattering phase functions derived from measured (volume-scattering meter, VSM) volume-scattering functions (VSFs) from Crimean coastal waters were found to have systematic differences in angular structure from Fournier-Forand (FF) functions with equivalent backscattering ratios. Hydrolight simulations demonstrated that differences in the angular structure of the VSF could result in variations in modeled subsurface radiance reflectances of up to +/-20%. Furthermore, differences between VSM and FF simulated reflectances were found to be nonlinear as a function of scattering and could not be explained with the single-scattering approximation. Additional radiance transfer modeling demonstrated that the contribution of multiple scattering to radiance reflectance increased exponentially from a minimum of 16% for pure water to a maximum of approximately 94% for turbid waters. Monte Carlo simulations demonstrated that multiple forward-scattering events were the dominant contributors to the generation of radiance reflectance signals for turbid waters and that angular structures in the shape of the VSF at forward angles could have a significant influence in determining reflectance signals for turbid waters.