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In spite of the negative electron affinity of Ne atoms, appreciable concentrations of electrons can be trapped in solid neon layers formed by depositing the gas on a cold substrate with concurrent electron irradiation. These are trapped at defect sites, and can be promoted into the conduction band in an annealing experiment. They can then recombine with positive charges producing vacuum ultraviolet "thermoluminescence," but can also be extracted from the solid, and detected as an "exoelectron" current. The thermally stimulated exoelectron emission profiles of the electron current versus temperature reveal two broad features near 7.5 and 10 K. These are shown to correspond to two distributions of electron trapping sites with slightly differing activation energies. For the narrower, higher temperature maximum, an average activation energy of about 23 meV is deduced, in good agreement with predictions based on the theory of electronic defect formation.

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We have studied thermostimulated luminenscence and electron emission of nitrogen films and nanoclusters containing atomic nitrogen free radicals. Thermostimulated electron emission from N 2 nanoclusters was observed for the first time. Thermostimulated luminescence spectra obtained during N 2 -He sample destruction are similar to those detected from N 2 films pre-irradiated by an electron beam. This similarity reveals common mechanisms of energy transfer and relaxation. The correlation of the luminescence intensity and the electron current in both systems points to the important role of ionic species in relaxation cascades. A sublimation of solid helium shells isolating nitrogen nanoclusters is a trigger for the initiation of thermostimulated luminescence and electron emission in these nitrogen-helium condensates. PACS: 78.60.Kn Thermoluminescence; 79.75.+g Exoelectron emission.