A unique ultrasonic online spectrophotometric system for kinetic measurements of homogeneous polar reactions under ultrasound was developed. The setup consists of an ultrasonic bath, an HPLC UV/Vis detector, an HPLC pump, a refrigerated heating circulator bath, and a data processing unit. An analogue-digital converter was constructed and a data processing program AD_com was written for registration of detector signal. The pH-independent hydrolysis of 4-nitrophenyl chloroacetate as a model reaction and also sonolytic degradation of 4-nitrophenol were used for the examination of the online spectrophotometric system. Preliminary kinetic studies proved that the system can be successfully applied for ultrasonic kinetic investigations of polar homogeneous reactions. This online system allows a sensitive and reproducible monitoring of various homogeneous processes, which can be detected spectrophotometrically under ultrasonic irradiation.

No abstract