FTIR spectroscopy was used to distinguish between beech (Fagus sylvatica L.) trees grown at five different sites; one in middle Germany close to Göttingen (forest district Reinhausen), three located in the southwest (two in Rhineland-Palatinate: forest districts Saarburg and Hochwald, and one in Luxembourg), and one in North-Rhine Westfalia. Detailed investigation of the spectra in the fingerprint region (1800–600 cm-1) revealed 16 distinct peaks and shoulders, most of which were assignable to wavenumbers previously shown to represent wood compounds. Differences in peak heights and peak ratios indicated differences in wood composition of beech trees from different sites. To determine if the wood of individual trees could be distinguished, principal component analysis (PCA) and cluster analysis were performed using FTIR spectra as input data. With both PCA and cluster analysis, trees from four of the five different sites were separated. It was not possible to distinguish between trees from Saarburg and Hochwald, where similar edaphic and climatic conditions exist, while wood spectra from trees from all other areas clearly segregated. Wood collected at different positions in the stem (bottom, crown, center and outer year rings) of trees grown at the same site was not distinguishable. Therefore, FTIR spectral analysis in combination with multivariate statistical methods can be used to distinguish wood of trees from different growth habitats. Extension of this method to other species may be of great interest for wood certification, as it may be possible to distinguish wood, of a given species, originating from different regions.
Fourier transform infrared attenuated total reflectance (FTIR-ATR) spectroscopy was combined with multivariate data analysis to investigate the chemical changes in wood during particle- and medium density fibreboard (MDF) production of grand fir (Abies grandis [Douglas ex D. Don] Lindl.) and European beech (Fagus sylvatica L.). The mechanical and technological properties of the novel particle- and fibreboards from beech or grand fir wood were similar to those of conventional panels from pine and spruce. This indicates that these timbers can be used as resources for wood-based panel production. Principal component analysis of FTIR spectra differentiated wood, fibres, particles, MDF, and particleboards of both species in the whole production process. Modifications in the spectra of fibres and particles suggested that cellulose properties of wood were changed during mechanical pulping. Different binders and hydrophobic additives were clearly traceable and discernable in wood composites. Samples from the same production step were clustered together, indicating high homogeneity of the raw materials, and intermediate and final products, respectively. This suggests that FTIR spectroscopy in combination with cluster analysis is a useful tool to assess product quality and can be further developed to control and optimize production processes for innovative wood-based panels.
Efficient end-of-life solutions play an important role in developing sustainable packaging because they contribute to reducing resource wastage and environmental impact, whilst providing economic and social benefits. This paper briefly reviews current end-of-life solutions for fibre and bio-based materials for packaging in Europe. It also addresses current research in the field, as well as standardization, legislation and socio-economic aspects related to renewable packaging in Europe. This review focuses on the following groups of packaging materials: paper and board and bioplastics. With this hierarchy, recycling, organic recovery and energy recovery are analysed with regard to the processes and technologies that offer the most sustainable end-of-life options.
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