Wireless optical communication systems allow reliable communication in the ultraviolet (UV) range, and protected from intentional suppression and interception, both in the presence and in the absence of direct visibility between the transmitter and the receiver. Currently, the actual and insufficiently explored direction is the development and research of mobile ad-hoc networks (MANET) with a UV communication channel. To analyze the capacity of a mobile network of UV communications with different spatial orientation of network nodes, it is necessary to take into account not only their coordinates and elevation angles but also azimuths. NLOS UV bandwidth models have been developed using three types of modulation: on-off keying (OOK), pulse-phase modulation (PPM), digital pulse interval modulation (DPIM) with a different number of guard intervals. The noted advantages of DPIM, which are most important for the implementation of a mobile self-organizing network with a UV channel, are: it does not require symbolic synchronization of the transmitter and receiver, it requires a smaller frequency band compared to PPM, it has a higher energy efficiency compared to OOK. A parametric approximation of losses in the NLOS UV channel has been performed, taking into account the azimuthal deviations of the transmitter and receiver for specific parameters of the communication system. Has been done a performance simulation of the MANET network with an ultraviolet communication channel Has been calculated values of the bit error rate (BER), and bit rate for a system with different types of modulation with low, medium, and high noise levels in the channel. With the use of parametric approximation of losses in the channel, are analyzed the BER and the bitrate of the UV communication system with an azimuthal deviation within 30 degrees. Based on the obtained simulation results, prospects for the further development of mobile self-organizing networks with a UV channel are indicated to improve their reliability and performance.