Die Grundlagen zur Auslegung von Schichtkristallisationsverfahren werden mitgeteilt. Ein besonderer Schwerpunkt ist hierbei die Ermittlung des erforderlichen Energiebedarfs. Wahrend des Ausfrierens der Kristallschichten muB ein Vielfaches der Kristallisationswarme ab-und beim anschlieflenden Aufschmelzen wieder zugefuhrt werden. Daher sind diese -taktweise durchgefiihrten -Verfahren nur bei sorgfaltiger apparativer Gestaltung und ProzeBfiihrung konkurrenzfahig zu anderen thermischen Trennverfahren, bei denen eine kontinuierliche Gegenstromfahrweise realisiert werden kann.Melt crystallization -Theoretical presumptions and technical limitations. The fundamentals of the design of melt crystallization processes on cooled surfaces are presented. Determination of the energy requirement is the essential point. During each freezing step a multiple of the heat of solidification must be removed and must be re-introduced during the subsequent melting step. Consequently, discontinuous processes of this nature can only compete with other thermal separation techniques -in which a continuous countercurrent operation can be realised -if the plant is well designed and the process is precisely controlled.
I Einleitung
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