Magnetron sputter deposition was applied to grow thin metal films in the presence of impurities. These impurities are ambient gas molecules and/or atoms from the residual gas present in the vacuum chamber. Seven materials were investigated: four single element metals (Al, Ag, Cu, and Cr), two widely applied alloys (Cu 55 Ni 45 and Ni 90 Cr 10), and one high entropy alloy (CoCrCuFeNi). The thin films were analyzed using X-ray diffraction to determine the domain size, the film texture, and the lattice parameter. The same trend for all studied materials is observed. When the ratio between the impurity and metal flux towards the substrate is low, the domain size is not affected by the presence of the impurities. In this regime, the incorporation of the impurities affects the lattice parameter. At high flux ratios, the change of the domain size can be described by a power law with the exponent equal to À1/2 for all studied materials. A kinetic Monte Carlo code is used to demonstrate this observed trend.
A methodology accounting for the contributions of static displacements of atoms to X-ray diffuse scattering by binary solid solutions with a face-centered cubic lattice was proposed. By microscopic accounting of static displacements of the atoms on the particular shell, we identified short- range order parameters on the first eight shells of Ni-13.1at. %W alloy from the intensity of X-ray diffuse scattering. The Fourier transform of static displacement of the atoms on every considered shell was calculated with the De Launay model using expressions of elements of dynamical matrix and Fourier transforms of quasi elastic forces, which are calculated by the pseudopotential method.
In this work inductively coupled plasma -mass spectrometry (ICP-MS) method was used to determine content of harmful to human health heavy elements such as As, Cd, Cr, Pb, Th, U, and other essential elements Zn, Cu, Ni in soil samples collected around fence of two largest in Asia copper (Oyu Tolgoi) and coal (Tavan Tolgoi) deposits. The analyses revealed average content of arsenic in the examined soil samples is exceeding 1.4 times the maximum permissible limit. It is consistent with many previous studies emphasizing on a high occurrence of arsenic in soils, well waters of North and Central Mongolia. But the contents of copper in soil samples collected from three leeward locations of the copper mine Oyu Tolgoi are up to 2.18 times higher than the maximum permitted content established by the government standard of Mongolia. The contents of Cd, Ni, Pb, U, and Zn in soil probes collected from leeward locations of Ukhaa Khudag open pit mine of Tavan Tolgoi coal deposit are higher than that of in probes collected from the windward side of that by factor ranging from 1.34 to 1.64. These facts indicate possible transport and spread of heavy elements by wind from these intense operating open pit mines into adjacent dry and windy deserted region of Mongolia.
Submicron-sized calcium carbonate (CaCO3) particles were prepared using an aerosol method in which two commercial air humidifiers containing 0.05 M of Na2CO3 and CaCl2 aqueous solutions were utilized as aerosol suppliers. Two streams of aerosols evaporated from the separate humidifiers were allowed to meet in 17-meter long, spiral reaction tube where collisions between two types of droplets containing precursor reagents leaded to grow of CaCO3 particles and precipitate onto the inner walls. XRD and SEM analysis revealed that CaCO3 particles were formed in calcite phase almost entirely.
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