The water vapor sorption behavior of a range of natural fibers (jute, flax, coir, cotton, hemp, Sitka spruce) has been studied. The data were analyzed using the Hailwood Horrobin model for isotherm fitting and determination of monolayer moisture content. The Hailwood Horrobin model was found to provide good fits to the experimental data. The extent of hysteresis exhibited between the adsorption and desorption isotherms was dependent on fiber type studied and was larger with high lignin compared with low lignin content fibers. The area bounded by the hysteresis loop decreased as the isotherms were performed at progressively higher temperatures. This behavior is consistent with sorption interactions occurring with a glassy solid below the glass transition
We compare - both analytically and numerically – two related spectral (≡ two-point) closures for the problem of the decay of temperature fluctuations convected by isotropic turbulence. The methods are the test-field model (TFM) (Kraichnan 1971; Newman & Herring 1979) and the eddy-damped quasinormal Markovian (ENQNM) approximation (Orszag 1974; Lesieur & Schertzer 1978). We show that EDQNM may be regarded as a rational approximation to, and simplification of, the TFM, except at small wavenumbers, where an additional eddy-dissipative term is needed to produce satisfactory results for the former. We consider three available methods for determining the relaxation timescales: (i) comparison with experiments, (ii) comparison with the direct-interaction approximation (DIA) in thermal equilibrium, and (iii) comparison with DIA at very small wavenumber, where it is believed to represent the dynamics properly. Comparison with both large Reynolds number and wind-tunnel Reynolds numbers is presented. For the latter, we discuss the relationship of the present theoretical results to the experiments of Warhaft & Lumley (1978) and Sreenivasan et al. (1980), and to the theoretical analysis of Corrsin (1964), Kerr & Nelkin (1980) and Antonopolos-Domis (1981).
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