In recent decades, scientists have
attempted to make more environmentally
friendly chemical synthesis procedures. One area of environmental
concern is the amount of electricity required to complete an experiment.
An effective means for minimizing the amount of electricity needed
to drive chemical reactions to completion is proposed through the
use of solar parabolic reflectors. The proposed solar reflectors are
assembled by covering unused satellite dishes with Mylar tape, giving
the satellite dish reflective properties when the dish is directed
at the sun. The ability to use the solar reflector as the sole heat
source for organic synthesis reactions is being considered. Comparative
studies will be conducted using electrical supplies to compare the
solar reflectors ability to generate heat to drive the chemical reactions
to completion. Analysis of the products of the reactions will be analyzed
using NMR and GC-MS. Preliminary research has shown that the solar
reflector is capable of heating a substance to a temperature over
300 °C, which is more than capable to drive most organic synthesis
reactions to completion. The synthesis of isobutyrophenone, which
is synthesized through a Friedel–Crafts acylation of benzene,
has been attempted using the solar reflector.
The Neuse River, North Carolina, U.S., exemplifies a typical de facto potable reuse scenario, where drinking water sources are located downstream of treated wastewater effluent discharges. The study results imply that planned potable water reuse, whether in an indirect or direct potable reuse scenario, might provide better control over water quality than the status quo conditions. Using fluorescence excitation-emission matrix (EEM) measurements, anthropogenic influence of a wastewater treatment plant (WWTP) discharge was observed in samples near the location of drinking water treatment plant (WTP) intakes, eight or more miles downstream of the WWTP, implying that anthropogenic compounds were not fully removed or degraded by natural processes in this reach of the river. PARAllel FACtor (PARAFAC) analysis supported a two-component model of humic-like and nonhumic-like dissolved organic matter (DOM). A nonmodeled anthropogenic feature was also indicated. Significantly, the quenched fluorescence of humic-like DOM (static and/or dynamic quenching) by nonhumic-like DOM-previously demonstrated for probe molecules but first reported here in a natural/anthropogenic-influenced system-offers exciting insight into studies of humic/nonhumic interactions with important implications for pollutant fate and transport, sensing applications, and water treatment. A molecular spectroscopic explanation for dual fluorescing peaks in amino acids and humic substances is postulated.
Semi-volatile in internal combustion engine lubricating oil may be responsible for limiting service life and can lead to in-cylinder deposit formation. In order to measure semivolatile content, a new thermogravimetric analysis (TGA) procedure has been adapted from existing soot procedures to determine the levels of semi-volatile compounds in progressively aged lubricating oil samples from a natural gas engine dynamometer test cell run. The per cent weight remaining at 550 °C, while heated at a constant rate in an inert atmosphere, varied linearly with running time, viscosity, and oxidation and nitration. The method yielded reproducible run-to-run results and showed good agreement between helium and argon atmospheres. Mass spectroscopy data confirmed increased levels of high molecular weight species during engine operation. This method may be applicable to diesel engine oil samples.
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