The isobaric phase equilibrium data for the binary systems
of ethanol
+ cyclopentanone, propyl butanoate + 4-methylphenol, and cyclopentanone
+ propane-1,2-diol at atmospheric pressure were measured using a modified
distillation apparatus. The Herington and Van Ness tests were employed
to confirm the thermodynamic consistency of the experimental data.
In addition, the Wilson, NRTL, and UNIQUAC models were used to correlate
experimental vapor–liquid equilibrium data. The corresponding
binary interaction parameters (BIPs) for the three models, which are
useful for the modeling and designing separation processes involving
biofuel, were obtained using a maximum likelihood objective function.
It has been confirmed that when appropriate BIPs are used in each
model, the outputs are consistent with each other and with experimental
data.
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