Iron oxide–Cu–Au (IOCG) deposits encompass a range of ore body shapes, including strata-bound replacement ores and hydrothermal breccias. We use the implicit method to make a detailed three-dimensional geological model of a strata-bound IOCG in the Cloncurry District, the E1 Group, to elucidate structural controls on mineralization. This model is compared with the nearby, world-class, Ernest Henry breccia-hosted IOCG deposit. Cu–Au mineralization in the E1 Group occurs as structurally controlled, mainly strata-bound, replacement bodies hosted in metasedimentary and metavolcaniclastic rocks intercalated with barren meta-andesite. Replacement bodies in the E1 Group conform to a series of NNW-plunging folds formed in regional D2 during peak metamorphism. Folding was followed by local D3/regional D4 shortening, which formed a dextral, transpressional Riedel brittle to ductile system along the regional Cloncurry Fault Zone. Modelling suggests that much of the Cu–Au mineralization is controlled by synthetic R structures associated with this Riedel system. The deformation sequence at Ernest Henry is comparable, but differences in host rock rheology, permeability and fluid pressure may explain the variation in ore body types and total Cu–Au resource between the two deposits. The results carry implications for other districts containing these styles of IOCG mineralization.
The Monakoff iron oxide-Cu-Au (IOCG) deposit, located to the north east of Cloncurry within the Eastern Succession of the Mount Isa Inlier, Queensland, Australia, is characterised by high concentrations of F and Ba, with a host of other enriched elements including Co, Ag, Mn, REE, U, Pb, Zn and Sr. This gives the deposit a characteristic gangue assemblage dominated by fluorite, barite and calcite. The nearby E1 deposit, located 25 km to the NNE of Monakoff, and the large Ernest Henry deposit, 3 km to the west of E1, also contain abundant fluorite, barite and calcite in late stage assemblages. The three deposits, therefore, constitute a distinct group of IOCG deposits within the district, based on their F-rich geochemical and mineralogical affinities.The Monakoff ore zone is hosted in dilational openings along a shear zone developed within metasediments and metavolcanic rocks at the boundary between competent hangingwall rocks of the Toole Creek Volcanics and footwall rocks of the Mount Norna Quartzites. Four stages of alteration and mineralisation are recognised: Stage 1 garnet-biotite alteration; Stage 2 biotite-magnetite alteration; Stage 3 main F-Ba-ore mineralisation; and a Stage 4 pyrite-alloclasite Au-Co-As overprint. The E1 deposit has a more complex history, but Stage 5 has veins of fluorite-barite-carbonate that are comparable to Monakoff's main stage. The Stage 3 assemblage at Monakoff comprises a sheared groundmass of fluorite, barite, manganoan calcite, magnetite, chalcopyrite, pyrite, galena and sphalerite, with coarser grained pods of the same mineralogy interpreted to be dilational structures infilled during syn-ore deformation. Accessory minerals include U-Pb-oxides, REE-F-carbonates and Ag-Pb-Bi-sulfosalts, with no discrete Au minerals. The sulfosalts are interpreted to have formed from an immiscible Bi-melt within the mineralising fluid at temperatures higher than the melting point of Bi. The Stage 4 overprint at Monakoff contains pyrite and alloclasite. Laser ablation analyses of the sulfide minerals at Monakoff reveal that Stage 3 sulfides contain only trace amounts of Au (0.04 ppm in pyrite), although galena and chalcopyrite contain significant concentrations of Ag. Stage 4 pyrite and alloclasite, however, contain ~1 ppm Au in solid solution and mass balance calculations indicate the majority of bulk rock Au to be present in these minerals, although the majority of bulk Ag is present in Stage 3 sulfides. The Stage 5 veins at E1 have an identical gangue and accessory mineralogy to Stage 3 at Monakoff and differ in the sulfide mineralogy only in the lack of galena and sphalerite.Four fluid inclusion populations are identified within the fluorite at Monakoff: Group 1 are CO2 rich; Group 2 are complex solid-liquid-vapour inclusions, with two groups based on homogenisation temperature (>450°C and 300-375°C). Laser ablation-ICP-MS analyses indicate these inclusions contain Cu, Pb, Zn, Fe, Mn, Mg, Ag, REE, U and Ba, but significantly no S, Se or Au; Group 3 are solidliquid-vapour inclusio...
Graphite Creek is an unusual flake graphite deposit located on the Seward Peninsula, Alaska, USA. We present field observations, uranium-lead (U–Pb) monazite and titanite geochronology, carbon (C) and sulfur (S) stable isotope geochemistry, and graphite Raman spectroscopy data from this deposit that support a new model of flake graphite ore genesis in high-grade metamorphic environments. The Graphite Creek deposit is within the second sillimanite metamorphic zone of the Kigluaik Mountains gneiss dome. Flake graphite, hosted in sillimanite-gneiss and quartz-biotite paragneiss, occurs as disseminations and in sets of very high grade (up to 50 wt.% graphite), semi-massive to massive graphite lenses 0.2 to 1 m wide containing quartz, sillimanite, inclusions of garnet porphyroblasts, K-feldspar, and tourmaline. Restitic garnet, sillimanite, graphite, and biotite accumulations indicate a high degree of anatexis and melt loss. Strong yttrium depletion in monazite, high europium ratios (Eu/Eu*), and excursions of high strontium and thorium concentrations are consistent with biotite dehydration melting. Monazite and titanite U–Pb ages record peak metamorphism from ~ 97 to 92 million years ago (Ma) and a retrograde event at ~ 85 Ma. Raman spectroscopy confirms the presence of carbonaceous material and highly ordered, crystalline graphite. Graphite δ13CVPDB values of − 30 to − 12‰ and pyrrhotite δ34SVCDT values of − 14 to 10‰ are consistent with derivation from organic carbon and sulfur in sedimentary rocks, respectively. These data collectively suggest that formation of massive graphite lenses occurred approximately synchronously with high-temperature metamorphism and anatexis of a highly carbonaceous pelitic protolith. Melt extraction and fluid release associated with anatexis were likely crucial for concentrating graphite. High-temperature, graphitic migmatite sequences within high-strain shear zones may be favorable for the occurrence of high-grade flake graphite deposits.
If Bach is the sound of God whistling while he works, then AC/DC is the sound of God ordering another round in a strip bar on a Saturday night. Led by the inimitable Bon Scott, AC/DC and hard rock acts of the second half of the 1970s established the macho sensibilities of the genre, while the appearance of 1950s nostalgia, American punk and new wave, and the anti-disco backlash were indicative of further trends affecting politics and pop culture. Deepening divisions of class, gender, and race—some of them ugly—were now being mirrored by all strands of the entertainment industry.
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