Clay-rich sediments from the Kajjansi, Kitiko, Kitetika, and Ntawo valleys in central Uganda were analyzed for mineralogical and chemical composition, including the rare earth element (REE) contents. The valleys are filled with Quaternary to Recent alluvial and lacustrine sands, silt, and gravels, which formed from the bed rock metasediments of the Buganda-Toro System and from granitoid rocks that include rocks of the basement. The mineralogical composition, REE contents, and elemental ratios in these sediments suggest a provenance from mainly felsic rocks, with only minor contributions from basic sources. The basic sediments were most likely derived from metasedimentary rocks, such as muscovite-biotite schists, which are characteristic of the Buganda-Toro System rocks, whereas the felsic sediments are derivatives of granitoid rocks of the basement. The most significant geochemical finding is that despite intense weathering, which has affected most elements, the REE, Th, and Sc remain immobile.
Catches of the economically important Nile tilapia (Oreochromis niloticus L.) from two eutrophic tropical lakes in Uganda, Lake Mburo and Murchison Bay, Lake Victoria, were examined to determine the presence of microcystins (MCs) in gut, liver and muscle of the fish. Analysis for MCs (RR, LR and YR) in both fish and water samples was by liquid chromatography coupled with mass spectroscopy (LC-MS) method. Physico-chemical parameters were also measured to establish the status of both lakes. MC-RR was the most prominent MC detected in Lake Mburo and Murchison Bay samples, there was no evidence of significant seasonal variation in the concentration of MCs in fish tissue. MCs were detected in all water samples from both study lakes. The mean concentration of MCs in water was found higher in dry times for Lake Mburo (P \ 0.05) and higher in wet times for Murchison Bay (P \ 0.05). MC concentrations in the fish guts were positively related with MC concentrations in water samples from Murchison bay (P \ 0.05), no such correlation was found in Lake Mburo. In eutrophic tropical lakes, fish seem to have a high tolerance to the toxicity of cyanotoxins including MCs. However, there is a possibility of accumulating these toxins in their tissue with the threat of transferring them higher up in the food chain. Due to a low sample size and short sampling period, the results can only serve to highlight the potential risk of MC accumulation in Nile tilapia in these lakes. Further studies are needed for the purpose of risk assessment.
Kaolin from the Buwambo deposit, located about 27 km north of Kampala (Uganda), has been analyzed for its mineralogical and chemical composition. The kaolin is derived from granite of the basement, which is exposed due to deeply weathered Buganda-Toro cover rocks. Kaolinite is the dominant mineral, with quartz and muscovite/illite as accessory minerals. Chemical data show that the kaolin is composed mainly of SiO 2 and Al 2 O 3 , with the other oxides being present in trace amounts. The depletion in Ti, Fe, Mn, Mg, Ca, Na, and K not only shows the extent of the kaolinization, but also gives Buwambo kaolin its almost white color. The kaolinization and weathering processes have enriched Ni and depleted other trace element contents in the Buwambo kaolin. The chondrite-normalized rare earth element (REE) patterns show enrichment in the light REEs, with a negative Ce anomaly. The REE pattern and the content of the other trace elements, show evidence of alteration and weathering processes related to kaolinization. The mineralogical and chemical compositions indicate that the kaolin is suitable for industrial use.
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