Recently, multifunctional devices printed on flexible substrates, with multisensing capability, have found new demand in practical fields of application, such as wearable electronics, soft robotics, interactive interfaces, and electronic skin design, revealing the vital importance of precise control of the fundamental properties of metal oxide nanomaterials. In this paper, a novel low-cost and scalable processing strategy is proposed to fabricate all-printed multisensing devices with UV- and gas-sensing capabilities. This undertaken approach is based on the hierarchical combination of the screen-printing process and laser irradiation post-treatment. The screen-printing is used for the patterning of silver interdigitated electrodes and the active layer based on anatase TiO2 nanoparticles, whereas the laser processing is utilized to fine-tune the UV and ethanol-sensing properties of the active layer. Different characterization techniques demonstrate that the laser fluence can be adjusted to optimize the morphology of the TiO2 film by increasing the contribution from volume porosity, to improve its electrical properties and enhance its UV photoresponse and ethanol-sensing characteristics at room temperature. Furthermore, results of the UV and ethanol-sensing investigation show that the optimized UV and ethanol sensors have good repeatability, relatively fast response/recovery times, and excellent mechanical flexibility.

This paper describes the fabrication and the characterization of an original example of a miniaturized resistive-type humidity sensor, printed on flexible substrate in a large-scale manner. The fabrication process involves laser ablation for the design of interdigitated electrodes on PET (Poly-Ethylene Terephthalate) substrate and a screen-printing process for the deposition of the sensitive material, which is based on TiO2 nanoparticles. The laser ablation process was carefully optimized to obtain micro-scale and well-resolved electrodes on PET substrate. A functional paste based on cellulose was prepared in order to allow the precise screen-printing of the TiO2 nanoparticles as sensing material on the top of the electrodes. The current against voltage (I–V) characteristic of the sensor showed good linearity and potential for low-power operation. The results of a humidity-sensing investigation and mechanical testing showed that the fabricated miniaturized sensors have excellent mechanical stability, sensing characteristics, good repeatability, and relatively fast response/recovery times operating at room temperature.

In this paper, we investigated the effect of humidity on paper substrates and propose a simple and low-cost method for their passivation using ZnO nanoparticles. To this end, we built paper-based microdevices based on an interdigitated electrode (IDE) configuration by means of a mask-less laser patterning method on simple commercial printing papers. Initial resistive measurements indicate that a paper substrate with a porous surface can be used as a cost-effective, sensitive and disposable humidity sensor in the 20% to 70% relative humidity (RH) range. Successive spin-coated layers of ZnO nanoparticles then, control the effect of humidity. Using this approach, the sensors become passive to relative humidity changes, paving the way to the development of ZnO-based gas sensors on paper substrates insensitive to humidity.

Cantilever-type all-organic microelectromechanical systems based on molecularly imprinted polymers for specific analyte recognition are used as chemical sensors. They are produced by a simple spray-coating-shadow-masking process. Analyte binding to the cantilever generates a measurable change in its resonance frequency. This allows label-free detection by direct mass sensing of low-molecular-weight analytes at nanomolar concentrations.