Ammonium aluminum carbonate hydroxide (AACH), a material isostructural with the mineral dawsonite (NaAl(OH) 2 CO 3 ), leads to finely dispersed and high-surface area Al 2 O 3 upon thermal decomposition. This family of compounds exhibit memory effect, i.e., the dawsonite structure can be recovered upon treatment of the derived aluminas in (NH 4 ) 2 CO 3 solutions at 323 K. Treatment of the oxides in water or NH 4 OH, NH 4 Cl, and Na 2 CO 3 solutions led to aluminum (oxi)hydroxides. The structural, morphological, and porous properties of the materials were investigated by ICP-OES, elemental analysis, XRD, FTIR and Raman spectroscopies, He pycnometry, TEM, gas (N 2 and Ar) adsorption, and thermal analysis (TGA and DSC). The reconstruction of dawsonite in ammonium carbonate was complete for the solids calcined at 523 and 723 K, consisting of a highly amorphous and low-skeleton-density alumina phase with well-developed porosity. The recrystallization was incomplete upon formation of larger γ-Al 2 O 3 crystals by calcination at 1073 K, and no reconstruction occurred when R-Al 2 O 3 was obtained by calcination at 1473 K. Characterization of the reconstructed samples indicates the attainment of NH 4 -dawsonite with higher purity than in the parent material. This is due to the presence of amorphous Al-containing phase-(s) in the as-synthesized sample coexisting with AACH. All the phases were selectively converted into dawsonite by thermal decomposition and (NH 4 ) 2 CO 3 treatment. The reformed samples consist of relatively large crystals with newly developed microporosity as compared to the parent material. These results extend the unique memory property of oxides derived from particular layered materials such as hydrotalcites to other families of mineral-like compounds.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.