The objective of this study was to identify the main sources of variation in pesticide losses at field and catchment scales using the dual permeability model MACRO. Stochastic simulations of the leaching of the herbicide MCPA (4-chloro-2-methylphenoxyacetic acid) were compared with seven years of measured concentrations in a stream draining a small agricultural catchment and one year of measured concentrations at the outlet of a field located within the catchment. MACRO was parameterized from measured probability distributions accounting for spatial variability of soil properties and local pedotransfer functions derived from information gathered in field- and catchment-scale soil surveys. At the field scale, a single deterministic simulation using the means of the input distributions was also performed. The deterministic run failed to reproduce the summer outflows when most leaching occurred, and greatly underestimated pesticide leaching. In contrast, the stochastic simulations successfully predicted the hydrologic response of the field and catchment and there was a good resemblance between the simulations and measured MCPA concentrations at the field outlet. At the catchment scale, the stochastic approach underestimated the concentrations of MCPA in the stream, probably mostly due to point sources, but perhaps also because the distributions used for the input variables did not accurately reflect conditions in the catchment. Sensitivity analyses showed that the most important factors affecting MACRO modeled diffuse MCPA losses from this catchment were soil properties controlling macropore flow, precipitation following application, and organic carbon content.
The process of interception was studied in 25-year-old dense stands of Norway spruce in South Sweden. The throughfall was measured intensively during one month and extensively during four growing seasons using water captured by large roofs and with randomly distributed funnel gauges. It was found that about 45% of the precipitation was lost as interception loss from this dense forest canopy. However, many sources of potential error, particularly in measurement of precipitation and throughfall, may be involved in quantifying the interception loss. The data set was used to test the interception part of a hydrological model, SOIL. The model uses a simple threshold formulation to calculate the accumulation of intercepted water in a single storage variable. The model was able to estimate fairly well the long-term cumulative interception loss from the forest canopy However, similarly to many other models, SOIL showed a pattern of overestimation of the interception loss during events with small precipitation and underestimation during events with large precipitation. It was concluded that the storage capacity was of major importance in modelling of long-term interception loss. Tree canopy water storage capacity on a leaf area basis was estimated to 0.7 mm which was three times larger than that obtained from a precipitation/throughfall graph.
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