This research aimed to determine the values of chemical properties and the relationships between the main pedoecological factors that characterize the soils in the Gurghiu Mountains. The mapping surveys were carried out on an area of 4,647.36 ha located in the mixed mountain forest sites (FM2) (1,000–1,400 m altitude). The area was stratified into homogeneous site units in terms of climate, hydricity, and trophicity. At the level of the elementary site units, 35 main soil profiles and 46 control profiles were placed. The number of profiles was determined statistically to ensure an error of no more than 10%. Soil samples collected from the main profiles were analyzed in the laboratory. Soil’s properties values decreased on the soil’s profile (humus content from 15 to 2%, nitrogen from 1.1 to 0.5%, sum of exchangeable hydrogen from 20 to 9 me/100 g soil, and total cationic exchange capacity from 38 to 20 me/100 g soil), except the pH and the base saturation degree (the pH increased on profile from 4.5 to 6, and the base saturation degree from 40 to 70%). The soil properties, except for moisture, were significantly affected by altitude, and decreased when the altitude increased. Soil trophicity can be characterized by a soil index, the values of which were between 17 and 42 for the analyzed soils. These values indicated soil-specific trophicity levels from oligotrophic to eutrophic.