A green, effective methodology for the preparation of water-based dispersions of poly(lactic acid) (PLA) for coating purposes is herein presented. The procedure consists of two steps: in the first one, an oil-in-water emulsion is obtained by mixing a solution of PLA in ethyl acetate with a water phase containing surfactant and stabilizer. Different homogenization methods as well as oil/water phase ratio, surfactant and stabilizer combinations were screened. In the second step, the quantitative evaporation of the organic provides water dispersions of PLA that are stable, at least, over several weeks at room temperature or at 4 °C. Particle size was in the 200–500 nm range, depending on the preparation conditions, as confirmed by scanning electron microscope (SEM) analysis. PLA was found not to suffer significant molecular weight degradation by gel permeation chromatography (GPC) analysis. Furthermore, two selected formulations with glass transition temperature (Tg) of 51 °C and 34 °C were tested for the preparation of PLA films by drying in PTFE capsules. In both cases, continuous films that are homogeneous by Fourier-transform infrared spectroscopy (FT-IR) and SEM observation were obtained only when drying was performed above 60 °C. The formulation with lower Tg results in films which are more flexible and transparent.

This is the "mobile" era, characterized by a growing demand of flexible substrates for novel products such as curved screens, folding smartphones, and wearable devices. In this framework, plastic electronics represents a suitable technology to replace silicon-based electronics. However, up to now, little attention has been devoted to rendering this technology more environmentally sustainable. It is thus necessary to develop new eco-designed devices that allow recycling of all the components and recovering the valuable materials through sustainable methods. For the first time, we report the fabrication of organic light emitting diodes made on an as-cast biopolymeric flexible substrate. Sodium alginate is a natural biodegradable polymer derived from brown algae; it is water-soluble and easy to manipulate for the realization of flat and transparent foils using an environmentally friendly process. Thus, the active stack can be directly deposited on the biopolymer substrate in a bottom-up architecture with no need for a pretreatment or a buffer layer. In addition, the devices can be disassembled and all of the valuable materials almost entirely recovered. This result opens up new and exciting opportunities for the fabrication of electronic and optoelectronic devices with a green platform for an ambient sustainable circular economy.