A new scanning tunneling microscope reactor used for high-pressure and high-temperature catalysis studies Review of Scientific Instruments 79, 084101 (2008) To enable atomic-scale observations of model catalysts under conditions approaching those used by the chemical industry, we have developed a second generation, high-pressure, high-temperature scanning tunneling microscope (STM): the ReactorSTM. It consists of a compact STM scanner, of which the tip extends into a 0.5 ml reactor flow-cell, that is housed in a ultra-high vacuum (UHV) system. The STM can be operated from UHV to 6 bars and from room temperature up to 600 K. A gas mixing and analysis system optimized for fast response times allows us to directly correlate the surface structure observed by STM with reactivity measurements from a mass spectrometer. The in situ STM experiments can be combined with ex situ UHV sample preparation and analysis techniques, including ion bombardment, thin film deposition, low-energy electron diffraction and x-ray photoelectron spectroscopy.

Spectroscopic-imaging scanning tunneling microscopy is a powerful technique to study quantum materials, with the ability to provide information about the local electronic structure with subatomic resolution. However, as most spectroscopic measurements are conducted without feedback to the tip, it is extremely sensitive to vibrations coming from the environment. This requires the use of laboratories with low-vibration facilities combined with a very rigid microscope construction. In this article, we report on the design and fabrication of an ultra-stable STM for spectroscopicimaging measurements that operates in ultra high vacuum and at low temperatures (4 K). We perform finite element analysis calculations for the main components of the microscope in order to guide design choices towards higher stiffness and we choose sapphire as the main material of the STM head. By combining these two strategies, we construct a STM head with measured lowest resonant frequencies above f 0 = 13 kHz for the coarse approach mechanism, a value three times higher than previously reported, and in good agreement with the calculations. With this, we achieve an average vibration level of ∼ 6 fm/ √ Hz, without a dedicated low-vibration lab. We demonstrate the microscope's performance with topographic and spectroscopic measurements on the correlated metal Sr 2 RhO 4 , showing the quasiparticle interference pattern in real and reciprocal space with high signal-to-noise ratio. a) allan@physics.leidenuniv.nl 1 arXiv:1810.09727v1 [physics.app-ph]