This paper deals with parameters’ identification of the Dual Phase Lag (DPL) thermal model of a 3D printed porous materials. The experiments were performed for two porous materials with different filling factors. The Laplace transform was applied for the heat transfer equation and together with different optimization methods it allowed to identify the thermal time constants of the DPL model. Several optimization methods were tested with known parameters in order to confirm the correctness of the parameters’ estimation.