Abstract.To increase the optical absorption in very thin a-Si films is relevant for more efficient and inexpensive photovoltaics. In this work we deposited TiO2 particles with a gas aggregation source on top of a-Si thin films and study the effect on optical absorption. When using thin films, anti-reflection and enhanced-reflection occurs depending on the thickness, which was employed in this study. The experiments were compared with finite difference time domain (FDTD) simulations which yielded good agreement. Both increased and decreased optical absorption was measured, depending on the photon energy range. This work demonstrates that by tailoring the various parameters, the TiO2 particles can contribute to increasing the efficiency of an a-Si based solar cell.

Abstract:The emission of an electron from a metal nanostructure under illumination and its subsequent acceleration in a plasmonic field forms a platform to extend these phenomena to deposited nanoparticles, which can be studied by state-of-the-art confocal microscopy combined with femtosecond optical excitation. The emitted and accelerated electrons leave defect tracks in the immersion oil, which can be revealed by thermoluminescence. These photographic tracks are read out with the confocal microscope and have a maximum length of about 80 µm, which corresponds to a kinetic energy of about 100 keV. This energy is consistent with the energy provided by the intense laser pulse combined with plasmonic local field enhancement. The results are discussed within the context of the rescattering model by which electrons acquire more energy. The visualization of electron tracks originating from plasmonic field enhancement around a gold nanoparticle opens a new way to study with confocal microscopy both the plasmonic properties of metal nano objects as well as high energy electron interaction with matter.

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