Graphical abstract

This study presents two strategies used to enhance the biological degradation of phenolic wastewaters. In the first one the operation of a sequencing batch biofilter added with granular activated carbon (SBB-AC) was studied. The second strategy presents the results of the automation of a sequencing batch reactor in order to optimize the reaction phase. In this case, the dissolved oxygen was employed to monitor and control the reactor. The results of the SBB-AC system, based on the configuration of the reactor, type and size of activated carbon and size of the packing material, are discussed. The system biodegraded efficiently (total phenol removals as high as 97%) high concentrations (600 mg/l) of a mixture of phenol, 4-chlorophenol, 2,4-dichlorophenol and 2,4,6-trichlorophenol. Maximal eliminated loads of 4.33 kg COD/m3-d were achieved. For the second strategy, the applicability of an optimal control for a SBR using the dissolved oxygen as the measured variable was demonstrated. When the reactor was operated under the time-optimal control strategy, the degradation time of 4-chlorophenol was reduced. A very satisfactory operation of the reactor was observed, since the removal efficiencies were around 99%.

The optimization of fabrication conditions for colloidal micron-sized oblates obtained by the deformation of an oil-in-hydrogel emulsion is reported. The influence of the type of emulsion stabilizer, ultrasonication parameters, and emulsion and gel mixing conditions was explored. The best conditions with which to obtain more uniform particles were using polyvinyl alcohol as an emulsion stabilizer mixed with the gelatine solution at 35 °C and slowly cooling to room temperature. Four fractionation methods were applied to oblates to improve their size uniformity. The iterative differential centrifugation method produced the best size polydispersity reduction.