An ester is found in small concentrations
in vegetative pineapple plants, with spectral characteristics in the
ultraviolet of an ester of p-coumaric acid. p-Coumaric acid is obtained after
hydrolysis, and the remaining aqueous hydrolysate indicates the presence of
quinic acid lactone on chromatograms. On the basis of neutral equivalent
determinations, boric acid conductivity and periodate oxidation experiments,
and analyses following mild hydrolysis, the structure of the ester is suggested
to be a quinyl-di-p-coumarate. It serves in the plant as a cofactor for
pineapple indoleacetic acid oxidase.
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