Water column inventories are calculated for bomb radiocarbon at all the stations occupied during the GEOSECS and NORPAX expeditions and for the available TTO stations. The pattern of global inventories obtained in this way suggests that a sizable portion of the bomb radiocarbon that entered the Antarctic, the northern Pacific, and the tropical ocean has been transported to the adjacent temperate zones. A strategy for utilizing these inventory anomalies as constraints on global ocean circulation models is presented. Essential to this strategy are the improvement of our knowledge of the pattern of wind speed over the ocean, the establishment of the wind speed dependence of the rate of gas exchange between the atmosphere and sea, and the continued mapping of the distribution of bomb‐produced radiocarbon in the sea.

An improved method has been developed for the separation of the natural and bomb components of the radiocarbon in the ocean. The improvement involves the use of a very strong correlation between natural radiocarbon and dissolved silica. This method is applied to radiocarbon measurements made on samples collected during the Geochemical Ocean Sections Study (GEOSECS), Transient Tracers in the Ocean (TTO) and South Atlantic Ventilation Experiment (SAVE) expeditions. On the basis of this new separation we provide not only an estimate of the global inventory of bomb 14C at the time of the GEOSECS survey but also the distribution of bomb radiocarbon along four thermocline isopycnals in each ocean. We also document the evolution of the bomb 14C inventory and penetration along thermocline isopycnals in the North Atlantic Ocean between the times of the GEOSECS (1972–1973) and TTO (1980–1982) surveys and in the South Atlantic Ocean between the times of the GEOSECS (1973) and SAVE (1987–1989) surveys. In addition, we show that the bomb tritium to bomb 14C ratio (expressed in the tritium unit (TU) 81 units/100‰) for waters entering the thermocline of the northern hemisphere is about 9 times higher than for those entering the southern hemisphere thermocline. This contrast offers long‐term potential as an indicator of inter‐hemispheric transport of upper ocean waters.

A parameter based on the sum of the concentrations of PO4 and O2 (divided by the Redfield coefficient‐ΔO2/δPO4) is used to separate the contributions of the northern and southern components to deep waters in the Atlantic. This separation allows the amount of radiocarbon lost by radiodecay and the amount of oxygen lost to respiration during residence in the deep Atlantic to be calculated. Maps of these quantities reveal strong west to east gradients and weak north to south gradients consistent with ventilation along the western boundary from both ends of the ocean coupled with mixing outward from the boundary. The O2 and 14C deficiences are highly correlated, suggesting an O2 utilization rate of 12 μm/kg per century. The apparent mean isolation time of water in the deep Atlantic is about 200 years.

A global picture of the water column inventories of bomb‐produced tritium is constructed from the GEOSECS data set. this picture is compared with that obtained by combining the bomb tritium input function of Weiss and Roether [1980] with the bomb radiocarbon calibrated lateral redistribution model of Broecker et al. [1985]. While differences between the calculated and observed distribution exist, they are surprisingly small. Tritium distributions calculated using the lateral redistribution model provide predictions of the changes to be expected in the next few decades. Such predictions are essential to the design of sound strategies for continued monitoring of the tritium transient.

ABSTRACT. We present &4C and 39Ar data collected in the Nansen, Amundsen and Makarov basins during two expeditions to the central Arctic Ocean (RV Polarstern cruises ARK P1/3, 1987 and ARK VIII/3,1991). The data are used, together with published e14C values, to describe the distribution of &"C in all major basins of the Arctic Ocean (Nansen, Amundsen, Makarov and Canada Basins), as well as the 39Ar distribution in the Nansen Basin and the deep waters of the Amundsen and Makarov Basins. From the combined &4C and 39Ar distributions, we derive information on the mean "isolation ages" of the deep and bottom waters of the Arctic Ocean. The data point toward mean ages of the bottom waters in the Eurasian Basin (Nansen and Amundsen Basins) of ca. 250-300 yr. The deep waters of the Amundsen Basin show slightly higher 3H concentrations than those in the Nansen Basin, indicating the addition of a higher fraction of water that has been at the sea surface during the past few decades. Correction for the bomb 14C added to the deep waters along with bomb 3H yields isolation ages for the bulk of the deep and bottom waters of the Amundsen Basin similar to those estimated for the Nansen Basin. This finding agrees well with the 39Ar data. Deep and bottom waters in the Canadian Basin (Makarov and Canada Basins) are very homogeneous, with an isolation age of ca. 450 yr. e14C and 39Ar data and a simple inverse model treating the Canadian Basin Deep Water (CBDW) as one well-mixed reservoir renewed by a mixture of Atlantic Water (29%), Eurasian Basin Deep Water (69%) and brine-enriched shelf water (2%) yield a mean residence time of CBDW of ca. 300 yr.