A system for transfer hydrogenation of alkenes, composed of a ruthenium metathesis catalyst and HCOOH, is presented. This operationally simple system can be formed directly after a metathesis reaction to effect hydrogenation of the metathesis product in a single-pot. These hydrogenation conditions are applicable to a wide range of alkenes and offer remarkable selectivity.

International audienceThe Turiec Basin (TB) of Slovakia formed in the Miocene when the West Carpathians escaped from the Alpine region. The 1,250-m-thick sedimentary Neogene fill of the basin preserved fossil leaves as well as endemic bivalves, gastropods, and ostracodes. The paleolimnologic changes recorded in the TB infill were derived from the most abundant fossils, the ostracodes. Five contemporaneous ostracode assemblages within the Late Miocene lacustrine system were distinguished through statistical analysis. These assemblages have low species similarity, between 2.1 and 24.1%, and are recognized by shape differences among the Candoninae. The ostracode assemblages, mollusca fossils, and Sr-isotope ratios suggest a low-salinity environment at the beginning of the Late Miocene, during a brief connection with the Central Paratethys. When the connection ceased, the basin became an isolated freshwater lake, with five zones differentiated ecologically and bathymetrically using the ostracode assemblages. Taxonomic comparison of the faunas of the TB and the freshwater to brackish Neogene basins of Europe demonstrates the endemic character of the TB ostracode fauna. The biologic characteristics of the ostracode families, along with the geology of the lake basin, suggest that the longevity of the Late Miocene lake probably exceeded 1 Ma

Since olefin metathesis transformation has become a favored synthetic tool in organic synthesis, more and more distinct non-metathetical reactions of alkylidene ruthenium complexes have been developed. Depending on the conditions applied, the same olefin metathesis catalysts can efficiently promote isomerization reactions, hydrogenation of C=C double bonds, oxidation reactions, and many others. Importantly, these transformations can be carried out in tandem with olefin metathesis reactions. Through addition of one portion of a catalyst, a tandem process provides structurally advanced products from relatively simple substrates without the need for isolation of the intermediates. These aspects not only make tandem catalysis very attractive from a practical point of view, but also open new avenues in (retro)synthetic planning. However, in the literature, the term "tandem process" is sometimes used improperly to describe other types of multi-reaction sequences. In this Concept, a number of examples of tandem catalysis involving olefin metathesis are discussed with an emphasis on their synthetic value.