General experimental details, gas chromatograms of 26, and 1H and ®F NMR spectra of 44, 45, and 47 (13 pages). Ordering information is given on any current masthead page.
A General Procedure for the Fluorodenitration of Aromatic Substrates.-Treatment of several nitroarenes, e.g. (I) and (III), with potassium fluoride in the presence of phthaloyl difluoride or tetrafluorophthaloyl difluoride as a nitrite ion trap results in fluorodenitration, forming the corresponding fluoroaromatic compounds ( II) and (IV) respectively. Analogously, the substituted fluorobenzenes (V) -(VIII) are synthesized. -(MAGGINI, M.; PASSUDETTI, M.; GONZALES-TRUEBA, G.; PRATO, M.; QUINTILY, U.; SCORRANO, G.; J. Org. Chem. 56 (1991) 22, 6406-6411; Centro Stud.
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