A simple and rapid microwave-assisted hydrothermal (MH) method is used to synthesize spinel-based ZnCo 2 O 4 anode material for Li-ion batteries. Microwaves provide a uniform and rapid formation of the oxide at a low temperature of 190 C for a short reaction time of 15 minutes. The crystallinity, pore size distribution, surface morphology and characteristics, crystal structure, surface morphologies and electrochemical properties of ZnCo 2 O 4 (ZCO) are carried out by using X-diffraction (XRD), BrunauerEmmett-Teller (BET) analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), cyclic voltammetry, impedance and cyclic performance, respectively. The initial discharge capacity of microwave-ZCO (M-400) is 1510 mA h g À1 , at a current rate of 100 mA g À1. After 30 cycles, the M-400 sample delivers a reversible capacity as high as 1334 mA h g À1 at 100 mA g À1. For 10C tests, M-400 demonstrates a capacity of more than 605 mA h g À1, which is superior to that of conventional ZCO samples synthesized by hydrothermal reaction (C-400). In subsequent cycles, the capacity of M-400 recovers to 1664 mA h g À1 with the current density back to 0.1C and the diffusivity was higher than C-400 by $18 times. The comparable high capacity of the MH method indicates that it could be a viable route to easily synthesize spinel oxides.