Oxygen vacancy levels are monitored during the oxidation of CO by CeO(2-δ) nanorods and Au-CeO(2-δ) nanorods, nanocubes, and nanopolyhedra by using Raman scattering. The first-order CeO(2) F(2g) peak near 460 cm(-1) decreases when this reaction is fast (fast reduction and relatively slow reoxidation of the surface), because of the lattice expansion that occurs when Ce(3+) replaces Ce(4+) during oxygen vacancy creation. This shift correlates with reactivity for CO oxidation. Increases in the oxygen deficit δ as large as ~0.04 are measured relative to conditions when the ceria is not reduced.

Under 980 nm excitation, the temperature dependence of five-photon UV (256 and 276 nm) upconversion luminescence in Yb³⁺-Er³⁺ codoped β-NaLuF₄ nanocrystals was studied from 303 K to 523 K. The ⁴D(7/2) and ⁴G(9/2) levels of Er³⁺ are confirmed to be thermally coupled levels. They are the highest energy states for optical thermometry known so far. By using fluorescence intensity ratio technique, optical temperature sensing characteristics based on the ⁴D(7/2)/⁴G(9/2) → ⁴I(15/2) transitions of Er³⁺ were reported here for the first time. The obtained sensitivity of this UV-based sensor is higher than that of green-based optical thermometer in low temperature range.

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