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Zr-oxide secondary building units construct metal–organic framework (MOF) materials with excellent gas adsorption properties and high mechanical, thermal, and chemical stability. These attributes have led Zr-oxide MOFs to be well-recognized for a wide range of applications, including gas storage and separation, catalysis, as well as healthcare domain. Here, we report structure search methods within the Cambridge Structural Database (CSD) to create a curated subset of 102 Zr-oxide MOFs synthesized to date, bringing a unique record for all researchers working in this area. For the identified structures, we manually corrected the proton topology of hydroxyl and water molecules on the Zr-oxide nodes and characterized their textural properties, Brunauer–Emmett–Teller (BET) area, and topology. Importantly, we performed systematic periodic density functional theory (DFT) calculations comparing 25 different combinations of basis sets and functionals to calculate framework partial atomic charges for use in gas adsorption simulations. Through experimental verification of CO2 adsorption in selected Zr-oxide MOFs, we demonstrate the sensitivity of CO2 adsorption predictions at the Henry’s regime to the choice of the DFT method for partial charge calculations. We characterized Zr-MOFs for their CO2 adsorption performance via high-throughput grand canonical Monte Carlo (GCMC) simulations and revealed how the chemistry of the Zr-oxide node could have a significant impact on CO2 uptake predictions. We found that the maximum CO2 uptake is obtained for structures with the heat of adsorption values >25 kJ/mol and the largest cavity diameters of ca. 6–7 Å. Finally, we introduced augmented reality (AR) visualizations as a means to bring adsorption phenomena alive in porous adsorbents and to dynamically explore gas adsorption sites in MOFs.

We present a pluggable radiation-tolerant 4-level Pulse-Amplitude-Modulation (PAM4) optical transmitter module called GBT20 (Giga-Bit Transmitter at 20 Gbps) for particle-physics experiments. GBT20 has an OSFP or firefly connector to input 16 bit data each at 1.28 Gbps. The GBT20 drives a VCSEL die with an LC lens or a VCSEL TOSA and interfaces an optical fiber with a standard LC connector. The minimum module, including the host connector, occupies 41 mm × 13 mm × 6 mm. At 20.48 Gbps, the minimum Transmitter Dispersion Eye Closure Quaternary (TDECQ) is around 0.7 dB. The power consumption is around 164 mW in the low-power mode. The SEE cross-section is below 7.5 × 10−14 cm2. No significant performance degrades after a TID of 5.4 kGy.

We present the design and test results of a novel data transmitter ASIC operating up to 20.48 Gbps with 4-level Pulse-Amplitude-Modulation (PAM4) for particle physics experiments. This ASIC, named GBS20, is fabricated in a 65 nm CMOS technology. Two serializers share a 5.12 GHz Phase Locked Loop (PLL) clock. The outputs from the serializers are combined into a PAM4 signal that directly drives a Vertical-Cavity-Surface-Emitting-Laser (VCSEL). The input data channels, each at 1.28 Gbps, are scrambled with an internal 27-1 Pseudo-Random Binary Sequence (PRBS), which also serves as a frame aligner. GBS20 is tested to work at 10.24 and 20.48 Gbps with a VCSEL-based Transmitter-Optical-Subassembly (TOSA). The power consumption of GBS20 is below 238 mW and reduced to 164 mW in the low-power mode.

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