Perovskite light emitting diodes (PeLEDs) have reached external quantum efficiencies (EQEs) over 21%. Their EQE, however, drops at increasing current densities (J) and their lifetime is still limited to just a few hours. The mechanisms leading to EQE roll‐off and device instability require thorough investigation. Here, improvement in EQE, EQE roll‐off, and lifetime of PeLEDs is demonstrated by tuning the balance of electron/hole transport into a mixed 2D/3D perovskite emissive layer. The mixed 2D/3D perovskite layer induces exciton confinement and beneficially influences the electron/hole distribution inside the perovskite layer. By tuning the electron injection to match the hole injection in such active layer, a nearly flat EQE for J = 0.1–200 mA cm−2, a reduced EQE roll‐off until J = 250 mA cm−2, and a half‐lifetime of ≈47 h at J = 10 mA cm−2 is reached. A model is also proposed to explain these improvements that account for the spatial electron/hole distributions.

Mixed 2D/3D perovskite films with self‐assembled quantum wells have significantly improved the performance of perovskite light emitting diodes (PeLEDs). In this work, such films are fabricated through a two‐step interdiffusion method that is widely employed in processing of perovskite solar cells, however, remains rarely explored for PeLEDs. The effects of incorporating large‐cation ligand, i.e., butylammonium bromide (BABr) into formamidinium lead bromide (FAPbBr3) based perovskites, in terms of film composition, morphology, optoelectronic properties as well as device performance are thoroughly investigated in this method. By modulating BABr:PbBr2 ratio in the precursor solution, the optimal device shows a maximum external quantum efficiency (EQE) of 7.36% at 147.7 mA cm−2 and a brightness of 37 720 Cd m−2 at 5 V. The performance is remarkably higher than a reference device without BABr that shows a maximum EQE of 2.53% and a brightness of 6190 Cd m−2 at 5 V. The versatility of this method is further extended to another large‐cation ligand, 4‐fluoro‐benzylammonium bromide (F‐BZABr), which leads to maximum EQE of 8.55%. This work indicates two‐step processed mixed 2D/3D perovskites are promising for bright green PeLEDs.

We provide insight into the driving mechanisms and requirements to create an electro-optic spatial light modulator based on a Barium Titanate waveguide and an optically transparent electrode cladding layer. We have developed a generic framework of electric field simulations and non-linear optics to create any desired modulation in an area of interest, applicable for liquid crystals, Pockels and Kerr cells. Targeting our device structure, we have evaluated several design parameters of the arbitrarily reprogrammable SLM, capable of optical beamforming and high-quality holograms.