Three microporous polyimides, MPI-1, MPI-2, and MPI-3, with uniform pores were synthesized via one-pot polycondensation from tetrakis(4-aminophenyl)methane, tris(4-aminophenyl)amine and 1,3,5tris(4-aminophenyl)benzene with pyromellitic dianhydride, respectively. The amorphous networks exhibit excellent thermal stability, large BET surface areas up to 1454 m 2 g −1 , and narrow pore size distribution in the range from 5 to 6 Å. Their adsorption−desorption isotherms of CO 2 are reversible, and the CO 2 uptakes at 273 K and 1 bar are up to 16.8 wt %. Moreover, based on the ratios of initial slopes of isotherms, the CO 2 /N 2 and CO 2 /CH 4 separation factors are as high as 102 and 12, respectively. The above CO 2 adsorption and separation properties are attributed to the presence of abundant electron-rich heteroatoms in the polyimide networks and the unifrom ultralmicroporous structures. In addition, for MPI-1, the adsorption capacity of benzene vapor is 119.8 wt %, while the separation factors of benzene over nitrogen and water reach 342 and 28, respectively. The outstanding selective adsorptions of CO 2 gas and benzene vapor endow the microporous polyimides with promising potential in CO 2 capture and separation as well as air-and water-cleaning applications.

The spinning mechanism of natural silk has been an open issue. In this study, both the conformation transition from random coil to b sheet and the b sheet aggregation growth of silk fibroin are identified in the B. mori regenerated silk fibroin aqueous solution by circular dichroism (CD) spectroscopy. A nucleation-dependent aggregation mechanism, similar to that found in prion protein, amyloid b (Ab) protein, and a-synuclein protein with the conformation transition from a soluble protein to a neurotoxic, insoluble b sheet containing aggregate, is a novel suggestion for the silk spinning process. We present evidence that two steps are involved in this mechanism: (a) nucleation, a ratelimiting step involving the conversion of the soluble random coil to insoluble b sheet and subsequently a series of thermodynamically unfavorable association of b sheet unit, i.e. the formation of a nucleus or seed; (b) once the nucleus forms, further growth of the b sheet unit becomes thermodynamically favorable, resulting a rapid extension of b sheet aggregation. The aggregation growth follows a first order kinetic process with respect to the random coil fibroin concentration. The increase of temperature accelerates the b sheet aggregation growth if the b sheet seed is introduced into the random coil fibroin solution. This work enhances our understanding of the natural silk spinning process in vivo.Keywords: silk fibroin; spinning mechanism; conformation transition; nucleation-dependent; CD spectroscopy.A number of studies have been reported silk processing techniques [1 -11], including those of spider and silkworm. However, the controlling factors that determine the efficiency of silk spinning at ambient temperature and normal pressure remains unclear [6 -8]. The silk fibroin in the silkworm gland possesses relatively low viscosity in a concentrated solution as a result of its storage in a liquid crystalline state before spinning [7 -9]. This is coupled with a low critical shear rate for inducing crystallization in aqueous solution [10], as well as the low draw ratios for the production of uniaxially aligned fibrous structures [11]. Theoretical elucidation of the mechanism for the natural silk spinning process has implications for material science, particularly in the design of engineering polymers.The primary sequence of silk fibroin of the B. mori silkworm predominantly consists of the -(Gly-Ala-Gly-AlaGly-Ser) 8 -motif [12]. It has been demonstrated that two types of conformations exist in the silk fibroin: silk I, a mainly coiled chain conformation in the present silk gland, and silk II which is formed by regularly aligned crystalline b sheet in the silk fibers [7]. Previous studies have suggested that the b sheet conformation can be induced in silkworm fibroin by a stretching force [13], and the formation of spider dragline silk also involves a stress-induced b sheet formation by extensional flow [14]. But the mechanism involved in the conversion of a hydrogel of silk fibroin in the silk I state into the silk II state remains...

Tetraphenyladamantane-based polyaminals with ultrasmall pore, large specific surface area and abundant CO2-philic aminal groups are successfully synthesized, which exhibit simultaneously high CO2 adsorption capacity of 17.6 wt % (4.0 mmol g–1, 273 K/1.0 bar) and high adsorption selectivities of CO2/N2 (104) and CO2/CH4 (24). Especially, at the low pressure, e.g., 0.15 bar, the CO2 uptake at 273 K can reach 8.7 wt % (1.97 mmol g–1). The adsorption/selectivity properties are superior to most of microporous organic polymers (MOPs) reported in the literature. Besides the outstanding CO2-capturing ability, the polymers also possess high uptakes of benzene and cyclohexane vapors up to 72.6 and 52.7 wt %, respectively. In addition, the effects of reaction activity and type of amino groups as well as the size and shape of building blocks on porous architecture of microporous polyaminals are studied. The disclosed results are helpful for the deep understanding of pore formation and interconnecting behavior in MOPs and therefore are of significant importance for the synthetic control of MOPs for a specific application in gas storage and capture of organic vapors.