The article provides a theoretical analysis of the organisation of "excellence" education in school practice. It presents sound implementation principles of "excellence acmeological" approach to teaching in rural schools and necessary organizational and pedagogical conditions of quality education with the involvement of highly qualified teachers to ensure the educational process and increase the motivation of students to study. The paper proposes organizational and technological implementation model of "excellence acmeological" teaching in rural schools. An objective assessment of the achievement of the expected results is ensured when educational organizations turn to qualified assessment centers in order to assess the level of training among students. Much attention is given to the problems of formation and evaluation of competencies of general secondary education graduates. The excellence acmeological idea of development and self-development directs an individual to become a successful person and a highly qualified specialist.