This paper aims to present a brief overview of different biosynthesis routes of silver nanoparticles (NPs), their applications and influence of the method used on the size and morphology of these nanoparticles. A detailed and comprehensive study of available biological methods, also referred to as a bottom-up approach, as well as techniques reported, have been provided with an eye for details and comparison between the techniques involving fungi, bacteria, algae and plant extracts. Plant-derived bioreductants such as leaf, stem or root extracts of various plants are seen as suitable solutions to green synthesis of silver NPs, implementing an easy, non-toxic, clean and environmentally friendly approach. Furthermore, reports on the antimicrobial activities with the zone of inhibition for various pathogens have also been included.
A novel double ceramic layered (DCL) CaZrO 3 /Yttria-stabilized zirconia (YSZ) thermal barrier coatings (TBCs) was designed for improved service life against sulfate vanadate hot corrosion as compared with that of YSZ single layered coating. The hot corrosion behavior of DCL CaZrO 3 /YSZ coatings was studied at 950°C after dry spreading 50%Na 2 SO 4 +50%V 2 O 5 mixture onto a coated surface.The CaZrO 3 as the topmost layer in DCL CaZrO 3 /YSZ coatings, served as a sacrificial layer during sulfate vanadate hot corrosion protecting the underneath YSZ coating. The corrosion reactions in this case were sluggish due to the initial formation of low melting point meta-calcium vanadate (CaV 2 O 6 ) that isothermally transformed to higher melting point calcium vanadates having higher calcia (CaO) content. The corrosion reaction products sealed the top surface, impeding the oxygen movement and eventually retarded the thermally grown oxide (TGO) growth.
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