Electroconductive fibers composed of cellulose and carbon nanotubes (CNTs) were spun using aqueous alkaline/urea solution. The microstructure and physical properties of the resulting fibers were investigated by scanning electron microscopy, Raman microscopy, wide-angle X-ray diffraction, tensile tests, and electrical resistance measurements. We found that these flexible composite fibers have sufficient mechanical properties and good electrical conductivity, with volume resistivities in the range of about 230-1 Ohm cm for 2-8 wt % CNT loading. The multifunctional sensing behavior of these fibers to tensile strain, temperature, environmental humidity, and liquid water was investigated comprehensively. The results show that these novel CNT/cellulose composite fibers have impressive multifunctional sensing abilities and are promising to be used as wearable electronics and for the design of various smart materials.
Clothing is one of the primary human needs, and the demand is met by the global production of thousands of tons of textile fibers, fabrics and garments every day. Polyester clothing manufactured from oil-based polyethylene terephthalate (PET) is the market leader. Conventional PET creates pollution along its entire value chain—during the production, use and end-of-life phases—and also contributes to the unsustainable depletion of resources. The consumption of PET garments thus compromises the quality of land, water and air, destroys ecosystems, and endangers human health. In this article, we discuss the different stages of the value chain for polyester clothing from the perspective of sustainability, describing current environmental challenges such as pollution from textile factory wastewater, and microfibers released from clothing during the laundry cycle. We also consider potential solutions such as enhanced reuse and recycling. Finally, we propose a series of recommendations that should be applied to polyester clothing at all stages along the value chain, offering the potential for meaningful and effective change to improve the environmental sustainability of polyester textiles on a global scale.
This research explains the melt spinning of bicomponent fibers, consisting of a conductive polypropylene (PP) core and a piezoelectric sheath (polyvinylidene fluoride). Previously analyzed piezoelectric capabilities of polyvinylidene fluoride (PVDF) are to be exploited in sensor filaments. The PP compound contains a 10 wt % carbon nanotubes (CNTs) and 2 wt % sodium stearate (NaSt). The sodium stearate is added to lower the viscosity of the melt. The compound constitutes the fiber core that is conductive due to a percolation CNT network. The PVDF sheath’s piezoelectric effect is based on the formation of an all-trans conformation β phase, caused by draw-winding of the fibers. The core and sheath materials, as well as the bicomponent fibers, are characterized through different analytical methods. These include wide-angle X-ray diffraction (WAXD) to analyze crucial parameters for the development of a crystalline β phase. The distribution of CNTs in the polymer matrix, which affects the conductivity of the core, was investigated by transmission electron microscopy (TEM). Thermal characterization is carried out by conventional differential scanning calorimetry (DSC). Optical microscopy is used to determine the fibers’ diameter regularity (core and sheath). The materials’ viscosity is determined by rheometry. Eventually, an LCR tester is used to determine the core’s specific resistance.
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