Eu 3+ -doped CaZrSi2O7 phosphors with promising luminescent properties have been successfully prepared through microwave heating. The crystallinity and luminescent performance were characterized by powder X-ray diffraction pattern, photoluminescence spectra, respectively.The results show that the obtained Eu 3+ -doped CaZrSi2O7 phosphors have good crystallinity, and strong emission under near-ultraviolet ( NUV) light excitation, which emits red colors peaking at 615 nm, corresponding to the 5 D0→ 7 F2 electric-dipole transition of Eu 3+ which shows the rare earth Eu 3+ ions are located in noncentrosymmetric sites.The red emission of Eu 3+ -doped CaZrSi2O7 phosphors is excellently consistent with CIE chromaticity standards. It is suggested that the as-prepared Eu 3+ -doped CaZrSi2O7 samples have high potential for phosphor-converted white LEDs application.

Bluish-green Ba 3 Si 6 O 9 N 4 :Eu 2+ phosphors were synthesized by two-step synthesis processes using BaSiO 3 as a precursor. The samples were prepared by high-temperature solid-state reaction, and investigated by X-ray diffraction (XRD) and fluorescence spectrometer photometer (PL) respec-tively. The results of XRD illustrated that two-step method was beneficial to improve phases of Ba 3 Si 6 O 9 N 4 :Eu 2+ phosphor and obtain higher crystallinity. The maximum luminescent intensi-ty of two-step process and high temperature solid-state method was obtained, when Eu 2+ doping amount was 9%. After calcul-ation, the distance of quenching was determined at 18.71 Ǻ. Compared the emission spectrum of two-step process(the emission peak at 498 nm) with high-temperature solid phase method (the emission peak at 517 nm) under the excitation of 330 nm, an apparent electrophoresis of the blue shift was existed. And the emission peak of two-step process was closer to the value of theoretical (480nm). The results of energy spectrum analysis clarified that the elements content of two-step method was closer to the theoretical stoichiometry ratio, which indicated that two-step preparation of Ba 3 Si 6 O 9 N 4 : Eu 2+ phosphor was an effective way to reduce the lattice defects.