The microwave permittivity and permeability of Carbon Nanotubes (CNTs)/paraffin and CNTs-Co(C)/paraffin were measured respectively and their differences were discussed in detail. Furthermore, the reflection losses for double-layer CNTs (CNTs-Co(C))/epoxy coatings, with the thickness ranged from 1.6-2 mm, were practically tested through Arc Method in 2.6-18 GHz frequence range. The results indicated that the reflection loss peak shifted towards low frequency and the peak value decreased with the coating thickening and possible mechanisms for the phenomena were given.
Wave-absorbing coating samples are fabricated with ZnO whisker, the absorbent and silicon resin coating as the binder.The influences of the content of ZnO whisker in the absorbing coating and the thickness of the coating on millimeter wave absorbing property are analyzed.With the increasing of the thickness, the absorbing performance of the sample is enhanced significantly , the results show that with a ZnO whisker mass of 50% and coating thickness of 2 mm, excellent absorption (R<-10dB) is observed in the wave band from 66 to 78 GHz (with a bandwidth of 12GHz) . When the ZnO whisker mass is reduced to 30% with the same thickness of 2mm, two absorption bands are obtained from 55 to 67 GHz (with a bandwidth 12GHz) and 100 to 110 GHz (with a bandwidth 10GHz). Maxwell equations and boundary conditions are used to analyze the absorbing mechanism of the coating.
The nano-powder of Al2O3-SiO2-CaF2 bio-glass was prepared by the homo-precipitation method with some inorganic salts containing Al3+, Ca2+, Na+, F-, SiO3 2+, Cl- as starting-reagents. The composition and characteristics of the powders were studied with XRD, EDAX, TEM and DTA. The results indicate that the prepared powder belongs to amorphous compounds containing Al, Ca, Si, O and F atoms and the size of particle is in the range of 30 ~ 70 nm. Adding citric acid and the well-controlled desiccation process can slightly improve the dispersing effect of the powders; the mixture ratio of the reagents rarely affects the characteristic of powder. The crystal phase CaF2 was precipitated firstly from the amorphous structure when the temperature is above 600°C, with the temperature rising, Al2SiO5 and Al4.4Si1.2O9.5 etc. crystal phases were precipitated sequentially.
The ultrafine glassy powder of Al-Si-Ca-P-O-F polynary system was prepared by liquid precipitation method with several inorganic compounds as reactants containing the ions such as Al3+, SiO32-, P3O105-, Ca2+, F-, respectively. The powder was heat-treated in the range of temperature from 773 to 1173K and its crystallized processes were ascertained. The morphology, composition, bonding state and structure, crystallized behavior of the glassy powder were characterized by means of TEM, XRD, EDAX, IR, DSC etc methods. The results show that the powder containing Al, Si, Ca, P, O, F elements belongs to typical amorphous state, and the particles appeared hollow and near spherical morphology with the size from 30 to 70nm. The hollow particles collapsed as plate like conglutination state and a series of crystallized phases CaF2, Al2SiO5, Ca2SiO4, and Ca3(PO4)2 were separated sequentially during heat treatment in the range of temperature above. The characteristics of the glassy powder are similar to those of popular melting-quenched glass of the system. The network structure of the glass was mainly formed by the tetrahedrons of [SiO4], [AlO4] and [PO4], which were linked by the oxygen atoms of the angle in the tetrahedrons.
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